Core-modified rubyrins containing dithienylethene moieties

Zhikuan Zhou; Yi Chang; Soji Shimizu; John Mack; Christian Schütt; Rainer Herges; Zhen Shen; Nagao Kobayashi

doi:10.1002/anie.201402711

Core-modified rubyrins containing dithienylethene moieties

Zhikuan Zhou, Yi Chang, Soji Shimizu, John Mack, Christian Schütt, Rainer Herges, Zhen Shen, Nagao Kobayashi

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Two stable core-modified rubyrins bearing one and two dithienylethene (DTE) units (1 and 2) have been synthesized. With one "closed-form" DTE unit, 1 shows aromaticity associated with its conjugated circuit of 26 π-electrons. In contrast, rubyrin 2 containing one "open-form" DTE unit has nonaromatic properties.

Original language	English
Pages (from-to)	6563-6567
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	25
DOIs	https://doi.org/10.1002/anie.201402711
Publication status	Published - 2014 Jun 16

Keywords

ACID plot
aromaticity
core-modified rubyrins
dithienylethene
macrocycles

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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AU - Zhou, Zhikuan

AU - Chang, Yi

AU - Shimizu, Soji

AU - Mack, John

AU - Schütt, Christian

AU - Herges, Rainer

AU - Shen, Zhen

AU - Kobayashi, Nagao

PY - 2014/6/16

Y1 - 2014/6/16

N2 - Two stable core-modified rubyrins bearing one and two dithienylethene (DTE) units (1 and 2) have been synthesized. With one "closed-form" DTE unit, 1 shows aromaticity associated with its conjugated circuit of 26 π-electrons. In contrast, rubyrin 2 containing one "open-form" DTE unit has nonaromatic properties.

AB - Two stable core-modified rubyrins bearing one and two dithienylethene (DTE) units (1 and 2) have been synthesized. With one "closed-form" DTE unit, 1 shows aromaticity associated with its conjugated circuit of 26 π-electrons. In contrast, rubyrin 2 containing one "open-form" DTE unit has nonaromatic properties.

KW - ACID plot

KW - aromaticity

KW - core-modified rubyrins

KW - dithienylethene

KW - macrocycles

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Core-modified rubyrins containing dithienylethene moieties

Abstract

Keywords

ASJC Scopus subject areas

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