Core-modified rubyrins containing dithienylethene moieties

Zhikuan Zhou; Yi Chang; Soji Shimizu; John Mack; Christian Schütt; Rainer Herges; Zhen Shen; Nagao Kobayashi

doi:10.1002/anie.201402711

Core-modified rubyrins containing dithienylethene moieties

Zhikuan Zhou, Yi Chang, Soji Shimizu, John Mack, Christian Schütt, Rainer Herges, Zhen Shen, Nagao Kobayashi

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Two stable core-modified rubyrins bearing one and two dithienylethene (DTE) units (1 and 2) have been synthesized. With one "closed-form" DTE unit, 1 shows aromaticity associated with its conjugated circuit of 26 π-electrons. In contrast, rubyrin 2 containing one "open-form" DTE unit has nonaromatic properties.

Original language	English
Pages (from-to)	6563-6567
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	25
DOIs	https://doi.org/10.1002/anie.201402711
Publication status	Published - 2014 Jun 16

Keywords

ACID plot
aromaticity
core-modified rubyrins
dithienylethene
macrocycles

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.201402711

Cite this

@article{558e88ae0cc14336a04a333a480b8f08,

title = "Core-modified rubyrins containing dithienylethene moieties",

abstract = "Two stable core-modified rubyrins bearing one and two dithienylethene (DTE) units (1 and 2) have been synthesized. With one {"}closed-form{"} DTE unit, 1 shows aromaticity associated with its conjugated circuit of 26 π-electrons. In contrast, rubyrin 2 containing one {"}open-form{"} DTE unit has nonaromatic properties.",

keywords = "ACID plot, aromaticity, core-modified rubyrins, dithienylethene, macrocycles",

author = "Zhikuan Zhou and Yi Chang and Soji Shimizu and John Mack and Christian Sch{\"u}tt and Rainer Herges and Zhen Shen and Nagao Kobayashi",

year = "2014",

month = jun,

day = "16",

doi = "10.1002/anie.201402711",

language = "English",

volume = "53",

pages = "6563--6567",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "25",

}

TY - JOUR

T1 - Core-modified rubyrins containing dithienylethene moieties

AU - Zhou, Zhikuan

AU - Chang, Yi

AU - Shimizu, Soji

AU - Mack, John

AU - Schütt, Christian

AU - Herges, Rainer

AU - Shen, Zhen

AU - Kobayashi, Nagao

PY - 2014/6/16

Y1 - 2014/6/16

N2 - Two stable core-modified rubyrins bearing one and two dithienylethene (DTE) units (1 and 2) have been synthesized. With one "closed-form" DTE unit, 1 shows aromaticity associated with its conjugated circuit of 26 π-electrons. In contrast, rubyrin 2 containing one "open-form" DTE unit has nonaromatic properties.

AB - Two stable core-modified rubyrins bearing one and two dithienylethene (DTE) units (1 and 2) have been synthesized. With one "closed-form" DTE unit, 1 shows aromaticity associated with its conjugated circuit of 26 π-electrons. In contrast, rubyrin 2 containing one "open-form" DTE unit has nonaromatic properties.

KW - ACID plot

KW - aromaticity

KW - core-modified rubyrins

KW - dithienylethene

KW - macrocycles

UR - http://www.scopus.com/inward/record.url?scp=84902315600&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84902315600&partnerID=8YFLogxK

U2 - 10.1002/anie.201402711

DO - 10.1002/anie.201402711

M3 - Article

AN - SCOPUS:84902315600

VL - 53

SP - 6563

EP - 6567

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 25

ER -

Core-modified rubyrins containing dithienylethene moieties

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this