Copper-catalyzed skeletal rearrangement of O-propargylic alkylaldoximes via N-O bond cleavage

Itaru Nakamura, Tomoki Iwata, Dong Zhang, Masahiro Terada

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

O-Propargylic oximes that possess a proton at the α-position of the oxime group were effectively converted to the corresponding oxiranyl N-alkenylimines via a 5-endo-dig cyclization followed by the cleavage of the N-O bond.

Original languageEnglish
Pages (from-to)206-209
Number of pages4
JournalOrganic letters
Volume14
Issue number1
DOIs
Publication statusPublished - 2012 Jan 6

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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