Coordination programming in the design of porous coordination polymers: Tuning of the electronic activity of frameworks for selective nitrogen monoxide trapping

Wataru Kosaka, Kayo Yamagishi, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, Hitoshi Miyasaka

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

A change of building block from [Ru2 II, II (p-FPhCO2)4] to [Ru2 II, II (4-F-2-OMe PhCO2)4] in a phenazine (phz)-bridged [Ru2 II, II] chain compound led to a high selectivity toward nitrogen monoxide (NO) in the adsorption characteristics. High selectivity was observed despite the fact that electronically negative sites that enable close contact with NO molecules are not present in the pores, in contrast to [Ru2 II, II (4-Cl-2-OMePhCO2)4 (phz)], which also exhibited selective NO adsorption.

Original languageEnglish
Pages (from-to)890-892
Number of pages3
JournalChemistry Letters
Volume43
Issue number6
DOIs
Publication statusPublished - 2014

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Coordination programming in the design of porous coordination polymers: Tuning of the electronic activity of frameworks for selective nitrogen monoxide trapping'. Together they form a unique fingerprint.

Cite this