Coordination polymers of lanthanides incorporating N,N′- ethylenebis(2-hydroxy-1-naphthylideneiminato): Syntheses and crystal structures

Wenqian Chen; Yanmei Chen; Wei Liu; Tao Lei; Qian Gao; Damin Kim; David Su; Wu Li; Yahong Li

doi:10.1080/00958972.2012.744002

Coordination polymers of lanthanides incorporating N,N′- ethylenebis(2-hydroxy-1-naphthylideneiminato): Syntheses and crystal structures

Wenqian Chen, Yanmei Chen, Wei Liu, Tao Lei, Qian Gao, Damin Kim, David Su, Wu Li, Yahong Li

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Reaction of Ln(NO₃)₃·6H₂O with H₂napn (H₂napn=N,N′-ethylenebis(2-hydroxy-1- naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H₂napn) (SCN)(C₂H₅OH)₂(NO ₃)₂]_n (1), [La(H₂napn) ₂(SCN)(NOM₃)₂]_n (2), and [Ln(H ₂napn)_1.5(NO₃)₃]_n [Ln=La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H₂napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (2-7) with lanthanides. Each metal center of 1-7 is nine-coordinate. Lanthanide contraction is observed in 3-7.

Original language	English
Pages (from-to)	4430-4440
Number of pages	11
Journal	Journal of Coordination Chemistry
Volume	65
Issue number	24
DOIs	https://doi.org/10.1080/00958972.2012.744002
Publication status	Published - 2012
Externally published	Yes

Keywords

Crystal structure
Lanthanide complexes
Schiff-base phthalen-ol

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

Access to Document

10.1080/00958972.2012.744002

Cite this

Coordination polymers of lanthanides incorporating N,N′- ethylenebis(2-hydroxy-1-naphthylideneiminato) : Syntheses and crystal structures. / Chen, Wenqian; Chen, Yanmei; Liu, Wei; Lei, Tao; Gao, Qian; Kim, Damin; Su, David; Li, Wu; Li, Yahong.

In: Journal of Coordination Chemistry, Vol. 65, No. 24, 2012, p. 4430-4440.

Research output: Contribution to journal › Article › peer-review

@article{9c865445f73c44e5be33b1803b416c07,

title = "Coordination polymers of lanthanides incorporating N,N′- ethylenebis(2-hydroxy-1-naphthylideneiminato): Syntheses and crystal structures",

abstract = "Reaction of Ln(NO3)3·6H2O with H2napn (H2napn=N,N′-ethylenebis(2-hydroxy-1- naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn) (SCN)(C2H5OH)2(NO 3)2]n (1), [La(H2napn) 2(SCN)(NOM3)2]n (2), and [Ln(H 2napn)1.5(NO3)3]n [Ln=La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (2-7) with lanthanides. Each metal center of 1-7 is nine-coordinate. Lanthanide contraction is observed in 3-7.",

keywords = "Crystal structure, Lanthanide complexes, Schiff-base phthalen-ol",

author = "Wenqian Chen and Yanmei Chen and Wei Liu and Tao Lei and Qian Gao and Damin Kim and David Su and Wu Li and Yahong Li",

note = "Funding Information: The authors appreciate the financial supports of Hundreds of Talents Program (2005012) of CAS, Natural Science Foundation of China (20872105, 21272167), a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institution, and Graduation Education Innovation Project in Jiangsu Province (CXZZ12_0808).",

year = "2012",

doi = "10.1080/00958972.2012.744002",

language = "English",

volume = "65",

pages = "4430--4440",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "24",

}

TY - JOUR

T1 - Coordination polymers of lanthanides incorporating N,N′- ethylenebis(2-hydroxy-1-naphthylideneiminato)

T2 - Syntheses and crystal structures

AU - Chen, Wenqian

AU - Chen, Yanmei

AU - Liu, Wei

AU - Lei, Tao

AU - Gao, Qian

AU - Kim, Damin

AU - Su, David

AU - Li, Wu

AU - Li, Yahong

N1 - Funding Information: The authors appreciate the financial supports of Hundreds of Talents Program (2005012) of CAS, Natural Science Foundation of China (20872105, 21272167), a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institution, and Graduation Education Innovation Project in Jiangsu Province (CXZZ12_0808).

PY - 2012

Y1 - 2012

N2 - Reaction of Ln(NO3)3·6H2O with H2napn (H2napn=N,N′-ethylenebis(2-hydroxy-1- naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn) (SCN)(C2H5OH)2(NO 3)2]n (1), [La(H2napn) 2(SCN)(NOM3)2]n (2), and [Ln(H 2napn)1.5(NO3)3]n [Ln=La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (2-7) with lanthanides. Each metal center of 1-7 is nine-coordinate. Lanthanide contraction is observed in 3-7.

AB - Reaction of Ln(NO3)3·6H2O with H2napn (H2napn=N,N′-ethylenebis(2-hydroxy-1- naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn) (SCN)(C2H5OH)2(NO 3)2]n (1), [La(H2napn) 2(SCN)(NOM3)2]n (2), and [Ln(H 2napn)1.5(NO3)3]n [Ln=La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (2-7) with lanthanides. Each metal center of 1-7 is nine-coordinate. Lanthanide contraction is observed in 3-7.

KW - Crystal structure

KW - Lanthanide complexes

KW - Schiff-base phthalen-ol

UR - http://www.scopus.com/inward/record.url?scp=84871236178&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84871236178&partnerID=8YFLogxK

U2 - 10.1080/00958972.2012.744002

DO - 10.1080/00958972.2012.744002

M3 - Article

AN - SCOPUS:84871236178

VL - 65

SP - 4430

EP - 4440

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

SN - 0095-8972

IS - 24

ER -

Coordination polymers of lanthanides incorporating N,N′- ethylenebis(2-hydroxy-1-naphthylideneiminato): Syntheses and crystal structures

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this