Heat capacity of Cs2 (18-crown-6)3 [Ni (dmit)2] 2 was measured by adiabatic calorimetry. A broad thermal anomaly was observed around 225 K. The entropy gain (about 52 J K-1 mol-1) is much larger than that expected for twofold disordering of 18-crown-6 assumed in the previous structure analysis. The shape of thermal anomaly was qualitatively explained by a linear Ising model developed for cooperative disordering in polymers. The 18-crown-6 molecules forming a one-dimensional chain in the crystal are orientationally disordered with moderate cooperativity.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry