Convergent assembly of polycyclic ethers via acyl radical addition to unactivated enol ether

Masayuki Inoue; Yuuki Ishihara; Shuji Yamashita; Masahiro Hirama

doi:10.1021/ol062349i

Convergent assembly of polycyclic ethers via acyl radical addition to unactivated enol ether

Masayuki Inoue, Yuuki Ishihara, Shuji Yamashita, Masahiro Hirama

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

(Diagram presented) A new convergent strategy for assembling 6/6- and 6/7-fused ether ring systems was developed. The key features in our method include Ag⁺-promoted facile formation of chemically labile enol ether from 0,S-acetal and addition of an acyl radical to unactivated enol ether to cyclize a six- or seven-membered ether ring.

Original language	English
Pages (from-to)	5801-5804
Number of pages	4
Journal	Organic letters
Volume	8
Issue number	25
DOIs	https://doi.org/10.1021/ol062349i
Publication status	Published - 2006 Dec 7

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol062349i

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abstract = "(Diagram presented) A new convergent strategy for assembling 6/6- and 6/7-fused ether ring systems was developed. The key features in our method include Ag+-promoted facile formation of chemically labile enol ether from 0,S-acetal and addition of an acyl radical to unactivated enol ether to cyclize a six- or seven-membered ether ring.",

author = "Masayuki Inoue and Yuuki Ishihara and Shuji Yamashita and Masahiro Hirama",

year = "2006",

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T1 - Convergent assembly of polycyclic ethers via acyl radical addition to unactivated enol ether

AU - Inoue, Masayuki

AU - Ishihara, Yuuki

AU - Yamashita, Shuji

AU - Hirama, Masahiro

PY - 2006/12/7

Y1 - 2006/12/7

N2 - (Diagram presented) A new convergent strategy for assembling 6/6- and 6/7-fused ether ring systems was developed. The key features in our method include Ag+-promoted facile formation of chemically labile enol ether from 0,S-acetal and addition of an acyl radical to unactivated enol ether to cyclize a six- or seven-membered ether ring.

AB - (Diagram presented) A new convergent strategy for assembling 6/6- and 6/7-fused ether ring systems was developed. The key features in our method include Ag+-promoted facile formation of chemically labile enol ether from 0,S-acetal and addition of an acyl radical to unactivated enol ether to cyclize a six- or seven-membered ether ring.

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Convergent assembly of polycyclic ethers via acyl radical addition to unactivated enol ether

Abstract

ASJC Scopus subject areas

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