Convergent and stereoselective method for synthesis of O-linked oxepane ring system by intramolecular radical cyclization

Makoto Sasaki, Masayuki Inoue, Tetsuji Noguchi, Atsuo Takeichi, Kazuo Tachibana

Research output: Contribution to journalArticlepeer-review

64 Citations (Scopus)

Abstract

A new strategy for the construction of O-linked oxepane ring system is described. The present method involves regioselective acetal cleavage by i- Bu2AlSePh and intramolecular radical cyclization by use of β- alkoxyacrylate.

Original languageEnglish
Pages (from-to)2783-2786
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number18
DOIs
Publication statusPublished - 1998 Apr 30
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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