Convenient synthesis of 1,1'-binaphthyl-2,2'-dicarboxylic acid

S. Oi, K. Matsunaga, T. Hattori, S. Miyano

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Two syntheses of 1,1'-binaphthyl-2,2'-dicarboxylic acid (4) in good yields are presented via the oxidation of the 2'-methyl substituent of isopropyl 2'-methyl-1,1'-binaphthyl-2-carboxylate (8), which is readily obtainable by the reaction of 2-methyl-1-naphthyl Grignard reagent 7 with isopropyl 1-isopropoxy-2-naphthoate (6).

Original languageEnglish
Pages (from-to)895-899
Number of pages5
JournalSynthesis
Issue number9
DOIs
Publication statusPublished - 1993

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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