Controlled reduction of Cu2+ to Cu+ with an N,O-type chelate under hydrothermal conditions to produce Cu2O nanoparticles

Takanari Togashi, Hidetsugu Hitaka, Satoshi Ohara, Takashi Naka, Seiichi Takami, Tadafumi Adschiri

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

N,O-type organic chelates reduced coordinated Cu2+ ions under hydrothermal reaction conditions to produce Cu2O/CuO nanoparticles. Chelates in which the N and O atoms are closely spaced produced smaller amounts of CuO nanoparticles, indicating their higher ability to reduce Cu2+ ions to Cu+ ions. [Cu(Gly)2]2 with the shortest ligand chain length produced only Cu2O nanoparticles and, therefore, can be used as a single molecule precursor for the synthesis of Cu2O nanoparticles.

Original languageEnglish
Pages (from-to)1049-1051
Number of pages3
JournalMaterials Letters
Volume64
Issue number9
DOIs
Publication statusPublished - 2010 May 15

Keywords

  • Chelate effect
  • CuO
  • Hydrothermal synthesis
  • Reduction

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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