Control of third-order nonlinear optical properties of singlet diradical square planar metal complexes involving o-semiquinonato type ligands

H. Fukui, H. Nagai, R. Kishi, T. Minami, H. Takahashi, T. Kubo, M. Nakano

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

We investigate the longitudinal static second hyperpolarizabilities (γ) of several square planar nickel, palladium and platinum complexes involving two bidentate o-semiquinonato type ligands. It turns out that the diradical character and γ value of this type of complex can be controlled by modifying the donor atoms and the metal core.

Original languageEnglish
Pages (from-to)2416-2418
Number of pages3
JournalSynthetic Metals
Volume159
Issue number21-22
DOIs
Publication statusPublished - 2009 Nov

Keywords

  • Hyperpolarizability
  • Nonlinear optics
  • Open-shell system
  • Transition metal complex

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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