Abstract
We investigate the longitudinal static second hyperpolarizabilities (γ) of several square planar nickel, palladium and platinum complexes involving two bidentate o-semiquinonato type ligands. It turns out that the diradical character and γ value of this type of complex can be controlled by modifying the donor atoms and the metal core.
Original language | English |
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Pages (from-to) | 2416-2418 |
Number of pages | 3 |
Journal | Synthetic Metals |
Volume | 159 |
Issue number | 21-22 |
DOIs | |
Publication status | Published - 2009 Nov |
Externally published | Yes |
Keywords
- Hyperpolarizability
- Nonlinear optics
- Open-shell system
- Transition metal complex
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
- Metals and Alloys
- Materials Chemistry