Control of the sign of exchange interactions in solvent-separated radical ion pairs

S. Tero-Kubota, K. Zikihara, T. Yago, Y. Kobori, K. Akiyama

Research output: Contribution to journalArticle

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Abstract

The chemically induced dynamic electron polarization spectra generated by the laser photolysis of several donor-acceptor systems have been studied to verify the solvent effects on the exchange interaction in solvent-separated radical ion pairs. It has been shown that the sign of the exchange interaction depends on the polarity of solvents. The individual reorganization energies have been determined for several solvent-separated radical ion pair systems.

Original languageEnglish
Pages (from-to)145-154
Number of pages10
JournalApplied Magnetic Resonance
Volume26
Issue number1-2
DOIs
Publication statusPublished - 2004 Jan 1

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

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  • Cite this

    Tero-Kubota, S., Zikihara, K., Yago, T., Kobori, Y., & Akiyama, K. (2004). Control of the sign of exchange interactions in solvent-separated radical ion pairs. Applied Magnetic Resonance, 26(1-2), 145-154. https://doi.org/10.1007/BF03166568