Control of methanol oxidation by ionic behavior in supercritical water

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22 Citations (Scopus)

Abstract

In supercritical water the rate of methanol oxidation was controlled by ionic behavior as follows: the oxidation rate of methanol decreased with increasing proton and hydroxide ion concentration, possibly due to stabilization of the reactant, while that of CO was suppressed by added protons and enhanced by added hydroxide ions.

Original languageEnglish
Pages (from-to)2270-2271
Number of pages2
JournalChemical Communications
Volume1
Issue number21
DOIs
Publication statusPublished - 2001

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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