Control of Gas Sorption Gate-opening in Solid Solutions of One-dimensional Coordination Polymers

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5 Citations (Scopus)

Abstract

An isostructural solid solution series of one-dimensional coordination polymers, [(Ru(1 1x)Rhx)2(2,4,5-Me3PhCO2)4(phz)] (x = 0, 0.1, 0.22, 0.39, 0.55, and 1; 2,4,5-Me3PhCO2 1 = 2,4,5-trimethylbenzoate; phz = phenazine), was prepared by mixing [Rh2 II,II(2,4,5-Me3PhCO2)4] with [Ru2 II,II(2,4,5-Me3PhCO2)4] in x:(1 1 x) reaction ratios, respectively. This series of compounds systematically tunes the gate-opening pressures for the adsorption of CO2 (195 K) and NO (121 K), suggesting a feasible and simple method to modulate the gate-opening pressures.

Original languageEnglish
Pages (from-to)1308-1311
Number of pages4
JournalChemistry Letters
Volume48
Issue number11
DOIs
Publication statusPublished - 2019

Keywords

  • Gas sorption properties
  • One-dimensional coordination polymers
  • Solid solutions

ASJC Scopus subject areas

  • Chemistry(all)

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