Control of charge instabilities in quasi-one-dimensional halogen-bridged nickel compounds

Masahiro Yamashita, Kazuo Inoue, Takehisa Furuta, Akimasa Ichikawa, Hiroshi Okamoto, Noriyoshi Kimura, Hiroshi Ohki, Ryuichi Ikeda, Hiroshi Kitagawa, Shunji Bandow, Koshiro Toriumi, Tadaoki Mitani, Tachi Ohishi, Hiroshi Miyamae

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Abstract

Quasi-one-dimensional halogen-bridged nickel compounds with nitrate counteranions, Ni(chxn)zX(N03)E (chxn=cyclohexanediamine; X=C1 and Br), and with Perchlorate counteranions, Nl(chxn)2X(C10A)e (X=C1 and Br) have been synthesized in order to control the charge instabilities. The Ni(chxn)eX(N03)2 were synthesized by both chemical and electrochemical methods. The crystal structure of Ni(chxn)2Br(NO3)2 has been determined by single-crystal X-ray diffraction method. In this compound, the Ni(chxn)E moieties are bridged by Br- ions to construct linear-chain structures and the hydrogen-bond networks of NH…O-N-O…HN which hold the chains are extended over the chains two-dimensionally. The bridging Br˜ ions are located at the midpoints between neighboring two Ni atoms along the chains with no Peierls distortion. The Ni(chxn)EX(C104)2 were synthesized by halogenation of 70 % HC10 solution of Ni(chxn)2(C10J2. The lattice constants of Ni(chxn)2Cl(C104)E were determined by X-ray powder pattern. The N1-C1-N1 distance of this compound is almost equal to that of Ni(chxn)2Cl3. but the interchain distance in the direction of counteranions is much longer than that in Ni(chxn)2Cl3. The electronic structure of Ni(chxn)2Cl(C104)2 was discussed on the basis of the results of electrical conductivity and temperature-dependence CP/MAS 13C NMR spectra.

Original languageEnglish
Pages (from-to)179-186
Number of pages8
JournalMolecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Volume256
Issue number1
DOIs
Publication statusPublished - 1994 Nov

ASJC Scopus subject areas

  • Condensed Matter Physics

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    Yamashita, M., Inoue, K., Furuta, T., Ichikawa, A., Okamoto, H., Kimura, N., Ohki, H., Ikeda, R., Kitagawa, H., Bandow, S., Toriumi, K., Mitani, T., Ohishi, T., & Miyamae, H. (1994). Control of charge instabilities in quasi-one-dimensional halogen-bridged nickel compounds. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 256(1), 179-186. https://doi.org/10.1080/10587259408039246