Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

Taniyuki Furuyama, Mitsuo Asai, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(V) or arsenic(V)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.

Original languageEnglish
Pages (from-to)15101-15104
Number of pages4
JournalChemical Communications
Volume50
Issue number95
DOIs
Publication statusPublished - 2014 Nov 4

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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