Contrasting magnetism of [Mn2III] and [Mr 2IIMn2III] squares

Takuto Matsumoto, Takuya Shiga, Mao Noguchi, Tatsuya Onuki, Graham N. Newton, Norihisa Hoshino, Motohiro Nakano, Hiroki Oshio

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)


Two tetranuclear manganese distorted square-shaped clusters, [Mn 4III(L1)42-OMe)4] · 2.5H2O (1)and [Mn2IIMn 2III(L2)4(H2O)2]-(PF 6)2·CHCl3-CH3OH-1.5H 2O (2) (H2L1 = 2-[3-(2-hydroxyphenyl)-1H-pyrazol-5-yl]-6- pyridinecarboxylic acid methyl ester; H2L2 = 2-[3-(2-hydroxyphenyl)- 1H-pyrazol-5-yl]-6-pyrldinecarboxylic acid ethyl ester), exhibit antiferromagnetic and ferromagnetic interactions between neighboring manganese ions, respectively.

Original languageEnglish
Pages (from-to)368-370
Number of pages3
JournalInorganic chemistry
Issue number2
Publication statusPublished - 2010 Jan 18
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry


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