Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation

Yoshitomo Kashiwagi; Qinghai Pan; Futoshi Kurashima; Chikara Kikuchi; Jun ichi Anzai; Tetsuo Osa

doi:10.1246/cl.1998.143

Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation

Yoshitomo Kashiwagi, Qinghai Pan, Futoshi Kurashima, Chikara Kikuchi, Jun ichi Anzai, Tetsuo Osa

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A poly(acrylic acid)-coated graphite felt electrode immobilizing all bioelectrochemical reaction components of ferrocene, diaphorase, NADH and alcohol dehydrogenase in the domain of the poly(acrylic acid) layer was applied to oxidize electrocatalytically cis-1,2-cyclohexanedimethanol and 3-methyl-1,5-pentanediol to (+)-(1R,6S)-cis-8-oxabicyclo[4.3.0]nonan-7-one and (3S)-3-methyl-δ-valerolactone, respectively, in a 0.15 M phosphate buffer (pH 8.0) at the constant potential of 0.45 V vs. SCE with high current efficiency (>92%) and high optical purity (>92%).

Original language	English
Pages (from-to)	143-144
Number of pages	2
Journal	Chemistry Letters
Issue number	2
DOIs	https://doi.org/10.1246/cl.1998.143
Publication status	Published - 1998 Jan 1

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.1998.143

Fingerprint Dive into the research topics of 'Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation'. Together they form a unique fingerprint.

Cite this

Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation. / Kashiwagi, Yoshitomo; Pan, Qinghai; Kurashima, Futoshi; Kikuchi, Chikara; Anzai, Jun ichi; Osa, Tetsuo.

In: Chemistry Letters, No. 2, 01.01.1998, p. 143-144.

Research output: Contribution to journal › Article › peer-review

@article{3ca4ee37a74f42948d0d5528dc9f1e46,

title = "Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation",

abstract = "A poly(acrylic acid)-coated graphite felt electrode immobilizing all bioelectrochemical reaction components of ferrocene, diaphorase, NADH and alcohol dehydrogenase in the domain of the poly(acrylic acid) layer was applied to oxidize electrocatalytically cis-1,2-cyclohexanedimethanol and 3-methyl-1,5-pentanediol to (+)-(1R,6S)-cis-8-oxabicyclo[4.3.0]nonan-7-one and (3S)-3-methyl-δ-valerolactone, respectively, in a 0.15 M phosphate buffer (pH 8.0) at the constant potential of 0.45 V vs. SCE with high current efficiency (>92%) and high optical purity (>92%).",

author = "Yoshitomo Kashiwagi and Qinghai Pan and Futoshi Kurashima and Chikara Kikuchi and Anzai, {Jun ichi} and Tetsuo Osa",

year = "1998",

month = jan,

day = "1",

doi = "10.1246/cl.1998.143",

language = "English",

pages = "143--144",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "2",

}

TY - JOUR

T1 - Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation

AU - Kashiwagi, Yoshitomo

AU - Pan, Qinghai

AU - Kurashima, Futoshi

AU - Kikuchi, Chikara

AU - Anzai, Jun ichi

AU - Osa, Tetsuo

PY - 1998/1/1

Y1 - 1998/1/1

N2 - A poly(acrylic acid)-coated graphite felt electrode immobilizing all bioelectrochemical reaction components of ferrocene, diaphorase, NADH and alcohol dehydrogenase in the domain of the poly(acrylic acid) layer was applied to oxidize electrocatalytically cis-1,2-cyclohexanedimethanol and 3-methyl-1,5-pentanediol to (+)-(1R,6S)-cis-8-oxabicyclo[4.3.0]nonan-7-one and (3S)-3-methyl-δ-valerolactone, respectively, in a 0.15 M phosphate buffer (pH 8.0) at the constant potential of 0.45 V vs. SCE with high current efficiency (>92%) and high optical purity (>92%).

AB - A poly(acrylic acid)-coated graphite felt electrode immobilizing all bioelectrochemical reaction components of ferrocene, diaphorase, NADH and alcohol dehydrogenase in the domain of the poly(acrylic acid) layer was applied to oxidize electrocatalytically cis-1,2-cyclohexanedimethanol and 3-methyl-1,5-pentanediol to (+)-(1R,6S)-cis-8-oxabicyclo[4.3.0]nonan-7-one and (3S)-3-methyl-δ-valerolactone, respectively, in a 0.15 M phosphate buffer (pH 8.0) at the constant potential of 0.45 V vs. SCE with high current efficiency (>92%) and high optical purity (>92%).

UR - http://www.scopus.com/inward/record.url?scp=0032373733&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032373733&partnerID=8YFLogxK

U2 - 10.1246/cl.1998.143

DO - 10.1246/cl.1998.143

M3 - Article

AN - SCOPUS:0032373733

SP - 143

EP - 144

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 2

ER -

Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this