Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation

Yoshitomo Kashiwagi; Qinghai Pan; Futoshi Kurashima; Chikara Kikuchi; Jun ichi Anzai; Tetsuo Osa

doi:10.1246/cl.1998.143

Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation

Yoshitomo Kashiwagi, Qinghai Pan, Futoshi Kurashima, Chikara Kikuchi, Jun ichi Anzai, Tetsuo Osa

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A poly(acrylic acid)-coated graphite felt electrode immobilizing all bioelectrochemical reaction components of ferrocene, diaphorase, NADH and alcohol dehydrogenase in the domain of the poly(acrylic acid) layer was applied to oxidize electrocatalytically cis-1,2-cyclohexanedimethanol and 3-methyl-1,5-pentanediol to (+)-(1R,6S)-cis-8-oxabicyclo[4.3.0]nonan-7-one and (3S)-3-methyl-δ-valerolactone, respectively, in a 0.15 M phosphate buffer (pH 8.0) at the constant potential of 0.45 V vs. SCE with high current efficiency (>92%) and high optical purity (>92%).

Original language	English
Pages (from-to)	143-144
Number of pages	2
Journal	Chemistry Letters
Issue number	2
DOIs	https://doi.org/10.1246/cl.1998.143
Publication status	Published - 1998 Jan 1

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.1998.143

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Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation. / Kashiwagi, Yoshitomo; Pan, Qinghai; Kurashima, Futoshi; Kikuchi, Chikara; Anzai, Jun ichi; Osa, Tetsuo.

In: Chemistry Letters, No. 2, 01.01.1998, p. 143-144.

Research output: Contribution to journal › Article › peer-review

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abstract = "A poly(acrylic acid)-coated graphite felt electrode immobilizing all bioelectrochemical reaction components of ferrocene, diaphorase, NADH and alcohol dehydrogenase in the domain of the poly(acrylic acid) layer was applied to oxidize electrocatalytically cis-1,2-cyclohexanedimethanol and 3-methyl-1,5-pentanediol to (+)-(1R,6S)-cis-8-oxabicyclo[4.3.0]nonan-7-one and (3S)-3-methyl-δ-valerolactone, respectively, in a 0.15 M phosphate buffer (pH 8.0) at the constant potential of 0.45 V vs. SCE with high current efficiency (>92%) and high optical purity (>92%).",

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AU - Kikuchi, Chikara

AU - Anzai, Jun ichi

AU - Osa, Tetsuo

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Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation

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