Consturuction of a complete bioelectrocatalytic electrode composed of alcohol dehydrogenase-and all electron-transfer components-modified graphite felt for diol oxidation

Yoshitomo Kashiwagi, Qinghai Pan, Futoshi Kurashima, Chikara Kikuchi, Jun ichi Anzai, Tetsuo Osa

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

A poly(acrylic acid)-coated graphite felt electrode immobilizing all bioelectrochemical reaction components of ferrocene, diaphorase, NADH and alcohol dehydrogenase in the domain of the poly(acrylic acid) layer was applied to oxidize electrocatalytically cis-1,2-cyclohexanedimethanol and 3-methyl-1,5-pentanediol to (+)-(1R,6S)-cis-8-oxabicyclo[4.3.0]nonan-7-one and (3S)-3-methyl-δ-valerolactone, respectively, in a 0.15 M phosphate buffer (pH 8.0) at the constant potential of 0.45 V vs. SCE with high current efficiency (>92%) and high optical purity (>92%).

Original languageEnglish
Pages (from-to)143-144
Number of pages2
JournalChemistry Letters
Issue number2
DOIs
Publication statusPublished - 1998 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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