Construction of the AG-ring unit of pinnatoxin A via intramolecular alkylation and aza-Wittig reaction

Jin Wang; Satoshi Sakamoto; Kei Kamada; Aiko Nitta; Takeshi Noda; Hiroki Oguri; Masahiro Hirama

Construction of the AG-ring unit of pinnatoxin A via intramolecular alkylation and aza-Wittig reaction

Jin Wang, Satoshi Sakamoto, Kei Kamada, Aiko Nitta, Takeshi Noda, Hiroki Oguri, Masahiro Hirama

New Industry Creation Hatchery Center (NICHe)

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

An efficient synthetic route to the spirally fused AG-ring model of pinnatoxin A has been devised using the intramolecular cyclization of epoxy nitrile followed by an aza-Wittig reaction to form a seven-membered cyclic imine.

Original language	English
Pages (from-to)	891-893
Number of pages	3
Journal	Synlett
Issue number	6
Publication status	Published - 2003 May 26

Keywords

Alkylation
Aza-Wittig reaction
Cyclic imine
Pinnatoxi A
Spiro ring

ASJC Scopus subject areas

Organic Chemistry

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title = "Construction of the AG-ring unit of pinnatoxin A via intramolecular alkylation and aza-Wittig reaction",

abstract = "An efficient synthetic route to the spirally fused AG-ring model of pinnatoxin A has been devised using the intramolecular cyclization of epoxy nitrile followed by an aza-Wittig reaction to form a seven-membered cyclic imine.",

keywords = "Alkylation, Aza-Wittig reaction, Cyclic imine, Pinnatoxi A, Spiro ring",

author = "Jin Wang and Satoshi Sakamoto and Kei Kamada and Aiko Nitta and Takeshi Noda and Hiroki Oguri and Masahiro Hirama",

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AU - Wang, Jin

AU - Sakamoto, Satoshi

AU - Kamada, Kei

AU - Nitta, Aiko

AU - Noda, Takeshi

AU - Oguri, Hiroki

AU - Hirama, Masahiro

PY - 2003/5/26

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AB - An efficient synthetic route to the spirally fused AG-ring model of pinnatoxin A has been devised using the intramolecular cyclization of epoxy nitrile followed by an aza-Wittig reaction to form a seven-membered cyclic imine.

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KW - Aza-Wittig reaction

KW - Cyclic imine

KW - Pinnatoxi A

KW - Spiro ring

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