Construction of oriented π-electron arrays based on two-dimensional supramolecular organizates

Masatsugu Shimomura, Olaf Karthaus, Kuniharu Ijiro

    Research output: Contribution to journalArticlepeer-review

    3 Citations (Scopus)

    Abstract

    Two-dimensional supramolecular organizates are shown to be powerful tools for constructing oriented π-electron arrays, which are applicable to molecular photonics devices and artificial photosynthesis. Complementary hydrogen bonding at the interface of an amphiphilic nucleobase monolayer can form two-dimensional stacking of base-pairs, which is expected to be an electron medium for photoinduced electron transfer as well as double-strand DNAs. DNAs are also immobilized as a monomolecular film of the polyion-complex with an amphiphilic cationic intercalator. A new type of monolayer-forming stilbene amphiphile having a trinitrofluorenylidene group is prepared for designing spatially separated electron donor and acceptor layers.

    Original languageEnglish
    Pages (from-to)61-65
    Number of pages5
    JournalSupramolecular Science
    Volume3
    Issue number1-3
    DOIs
    Publication statusPublished - 1996 Jan 1

    ASJC Scopus subject areas

    • Engineering(all)

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