TY - JOUR
T1 - Construction of an Artificial Ferrimagnetic Lattice by Lithium Ion Insertion into a Neutral Donor/Acceptor Metal-Organic Framework
AU - Taniguchi, Kouji
AU - Narushima, Keisuke
AU - Mahin, Julien
AU - Kosaka, Wataru
AU - Miyasaka, Hitoshi
N1 - Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2016/4/18
Y1 - 2016/4/18
N2 - Construction of a molecular system in which the magnetic lattice exhibits long-range order is one of the fundamental goals in materials science. In this study, we demonstrate the artificial construction of a ferrimagnetic lattice by doping electrons into acceptor sites of a neutral donor/acceptor metal-organic framework (D/A-MOF). This doping was achieved by the insertion of Li-ions into the D/A-MOF, which was used as the cathode of a Li-ion battery cell. The neutral D/A-MOF is a layered system composed of a carboxylate-bridged paddlewheel-type diruthenium(II,II) complex as the donor and a TCNQ derivative as the acceptor. The ground state of the neutral form was a magnetically disordered paramagnetic state. Upon discharge of the cell, spontaneous magnetization was induced; the transition temperature was variable. The stability of the magnetically ordered lattice depended on the equilibrium electric potential of the D/A-MOF cathode, which reflected the electron-filling level. A ferrimagnetic order lattice has been artificially constructed by electron doping by lithium ion insertion from a magnetically disordered ground state in a neutral donor/acceptor metal-organic framework (D/A-MOF). The stability of the magnetically ordered lattice depends on the equilibrium potential of the D/A-MOF cathode. The results suggest a new strategy and direction for the design of molecule-based magnets.
AB - Construction of a molecular system in which the magnetic lattice exhibits long-range order is one of the fundamental goals in materials science. In this study, we demonstrate the artificial construction of a ferrimagnetic lattice by doping electrons into acceptor sites of a neutral donor/acceptor metal-organic framework (D/A-MOF). This doping was achieved by the insertion of Li-ions into the D/A-MOF, which was used as the cathode of a Li-ion battery cell. The neutral D/A-MOF is a layered system composed of a carboxylate-bridged paddlewheel-type diruthenium(II,II) complex as the donor and a TCNQ derivative as the acceptor. The ground state of the neutral form was a magnetically disordered paramagnetic state. Upon discharge of the cell, spontaneous magnetization was induced; the transition temperature was variable. The stability of the magnetically ordered lattice depended on the equilibrium electric potential of the D/A-MOF cathode, which reflected the electron-filling level. A ferrimagnetic order lattice has been artificially constructed by electron doping by lithium ion insertion from a magnetically disordered ground state in a neutral donor/acceptor metal-organic framework (D/A-MOF). The stability of the magnetically ordered lattice depends on the equilibrium potential of the D/A-MOF cathode. The results suggest a new strategy and direction for the design of molecule-based magnets.
KW - donor-acceptor systems
KW - electronic structure
KW - lithium batteries
KW - magnetic properties
KW - metal-organic frameworks
UR - http://www.scopus.com/inward/record.url?scp=84961282387&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84961282387&partnerID=8YFLogxK
U2 - 10.1002/anie.201601672
DO - 10.1002/anie.201601672
M3 - Article
AN - SCOPUS:84961282387
VL - 55
SP - 5238
EP - 5242
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 17
ER -