Construction of a one-dimensional chain composed of Mn6 clusters and 4,4′-bipyridine linkers: The first step for creation of "nano-dots-wires"

Kazuya Nakata; Hitoshi Miyasaka; Kunihisa Sugimoto; Tomohiko Ishii; Ken Ichi Sugiura; Masahiro Yamashita

doi:10.1246/cl.2002.658

Construction of a one-dimensional chain composed of Mn₆ clusters and 4,4′-bipyridine linkers: The first step for creation of "nano-dots-wires"

Kazuya Nakata, Hitoshi Miyasaka, Kunihisa Sugimoto, Tomohiko Ishii, Ken Ichi Sugiura, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Treatment of a mixed-valence Mn₆ cluster, [Mn₆O₂(t-BuCO₂)₁₀ (t-BuCO₂H)₄] (1), with 4,4′-bipyridine (bpy) in dichloromethane/1,2-dichloroethane solution gave a one-dimensional polymeric chain compound, [Mn₆O₂(t-BuCO₂)₁₀ (t-BuCO₂H)₂(bpy)] (2), in which the parent cluster cote was maintained as a building block.

Original language	English
Pages (from-to)	658-659
Number of pages	2
Journal	Chemistry Letters
Issue number	7
DOIs	https://doi.org/10.1246/cl.2002.658
Publication status	Published - 2002 Jul 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Treatment of a mixed-valence Mn6 cluster, [Mn6O2(t-BuCO2)10 (t-BuCO2H)4] (1), with 4,4′-bipyridine (bpy) in dichloromethane/1,2-dichloroethane solution gave a one-dimensional polymeric chain compound, [Mn6O2(t-BuCO2)10 (t-BuCO2H)2(bpy)] (2), in which the parent cluster cote was maintained as a building block.",

author = "Kazuya Nakata and Hitoshi Miyasaka and Kunihisa Sugimoto and Tomohiko Ishii and Sugiura, {Ken Ichi} and Masahiro Yamashita",

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doi = "10.1246/cl.2002.658",

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T2 - The first step for creation of "nano-dots-wires"

AU - Nakata, Kazuya

AU - Miyasaka, Hitoshi

AU - Sugimoto, Kunihisa

AU - Ishii, Tomohiko

AU - Sugiura, Ken Ichi

AU - Yamashita, Masahiro

PY - 2002/7/5

Y1 - 2002/7/5

N2 - Treatment of a mixed-valence Mn6 cluster, [Mn6O2(t-BuCO2)10 (t-BuCO2H)4] (1), with 4,4′-bipyridine (bpy) in dichloromethane/1,2-dichloroethane solution gave a one-dimensional polymeric chain compound, [Mn6O2(t-BuCO2)10 (t-BuCO2H)2(bpy)] (2), in which the parent cluster cote was maintained as a building block.

AB - Treatment of a mixed-valence Mn6 cluster, [Mn6O2(t-BuCO2)10 (t-BuCO2H)4] (1), with 4,4′-bipyridine (bpy) in dichloromethane/1,2-dichloroethane solution gave a one-dimensional polymeric chain compound, [Mn6O2(t-BuCO2)10 (t-BuCO2H)2(bpy)] (2), in which the parent cluster cote was maintained as a building block.

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Construction of a one-dimensional chain composed of Mn₆ clusters and 4,4′-bipyridine linkers: The first step for creation of "nano-dots-wires"

Abstract

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