Conformation effect of oligosilane linker on photoinduced electron transfer of tetrasilane-linked zinc porphyrin-[60]fullerene dyads

Yuki Shibano, Mikio Sasaki, Hayato Tsuji, Yasuyuki Araki, Osamu Ito, Kohei Tamao

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

A series of zinc porphyrin-[60]fullerene dyads linked by conformation-constrained tetrasilanes and permethylated tetrasilane have been synthesized for the evaluation of the conformation effect of the tetrasilane linkers on the photoinduced electron transfer. The excited-state dynamics of these dyads have been studied using the time-resolved fluorescence and absorption measurements. The fluorescence of the zinc porphyrin moiety in each dyad was quenched by the electron transfer to the fullerene moiety. The transient absorption measurements revealed that the final state of the excited-state process was a radical ion pair with a radical cation on the zinc porphyrin moiety and a radical anion on the fullerene moiety as a result of the charge separation. The charge separation and charge recombination rates were found to show only slight conformation dependence of the tetrasilane linkers, which is characteristic for the Si-linkages.

Original languageEnglish
Pages (from-to)356-367
Number of pages12
JournalJournal of Organometallic Chemistry
Volume692
Issue number1-3
DOIs
Publication statusPublished - 2007 Jan 1

Keywords

  • Conformation
  • Electron transfer
  • Fullerene
  • Oligosilane
  • Porphyrin

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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