Conformation change of nanosized silicon-organic polymer oriented into ordered nanoporous silicas

N. Ostapenko, G. Dovbeshko, N. Kozlova, S. Suto, A. Watanabe

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

We present a study of fluorescence (5-250)K and FTIR spectra of poly(di-n-hexylsilane) incorporated into nanoporous silicas (MCM-41 and SBA-15 types) and SiO2 aerosil. It is shown that the essential local conformation change of the polymer chain occurs only for the polymer embedded into and oriented in small-diameter pores with a large number of Si-OH groups on the surface of the walls. The competition between the polymer-surface and the polymer-polymer interactions leads to the restructuring of a polymer incorporated into the large pores of SBA-15 where the separarate polymer chain having trans- and gauche-conformations as well as the aggregates can be found. The presence of the gauche-conformation is confirmed by the shift of CHa2 and CHs2 stretching vibrations and, additionally, by the redistrubution of their intensity with increasing the pore diameter.

Original languageEnglish
Pages (from-to)8944-8948
Number of pages5
JournalThin Solid Films
Volume516
Issue number24
DOIs
Publication statusPublished - 2008 Oct 31

Keywords

  • Fluorescence and Fourie Transform Infrared (FTIR) spectra
  • Nanoporous silicas
  • Nanosized poly(di-n-hexylsilane)
  • SiO aerosil

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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