Confirmation by IR of the preferred conformations of CFTA esters in solution: A highly reliable criterion for the stereochemistry assignment of chiral alcohols

Kenji Omata, Kohsuke Kotani, Kuninobu Kabuto, Tomoya Fujiwara, Yoshio Takeuchi

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Direct confirmation of the preferred conformation of diastereomeric esters derived from a chiral secondary alcohol and a chiral derivatizing agent in solution, which is crucial for reliable NMR-based assignment of absolute stereochemistry of the alcohol, has been attained for the first time by examination of IR spectra of the CFTA esters.

Original languageEnglish
Pages (from-to)3610-3612
Number of pages3
JournalChemical Communications
Volume46
Issue number20
DOIs
Publication statusPublished - 2010 May 21

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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