Confirmation by IR of the preferred conformations of CFTA esters in solution: A highly reliable criterion for the stereochemistry assignment of chiral alcohols

Kenji Omata; Kohsuke Kotani; Kuninobu Kabuto; Tomoya Fujiwara; Yoshio Takeuchi

doi:10.1039/b926793j

Confirmation by IR of the preferred conformations of CFTA esters in solution: A highly reliable criterion for the stereochemistry assignment of chiral alcohols

Kenji Omata, Kohsuke Kotani, Kuninobu Kabuto, Tomoya Fujiwara, Yoshio Takeuchi

Division of Developmental Research in Education Programs

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Direct confirmation of the preferred conformation of diastereomeric esters derived from a chiral secondary alcohol and a chiral derivatizing agent in solution, which is crucial for reliable NMR-based assignment of absolute stereochemistry of the alcohol, has been attained for the first time by examination of IR spectra of the CFTA esters.

Original language	English
Pages (from-to)	3610-3612
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	20
DOIs	https://doi.org/10.1039/b926793j
Publication status	Published - 2010 May 21

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b926793j

Cite this

@article{8c5ac6fe79a44d719fd28f2cfb7779a5,

title = "Confirmation by IR of the preferred conformations of CFTA esters in solution: A highly reliable criterion for the stereochemistry assignment of chiral alcohols",

abstract = "Direct confirmation of the preferred conformation of diastereomeric esters derived from a chiral secondary alcohol and a chiral derivatizing agent in solution, which is crucial for reliable NMR-based assignment of absolute stereochemistry of the alcohol, has been attained for the first time by examination of IR spectra of the CFTA esters.",

author = "Kenji Omata and Kohsuke Kotani and Kuninobu Kabuto and Tomoya Fujiwara and Yoshio Takeuchi",

year = "2010",

month = may,

day = "21",

doi = "10.1039/b926793j",

language = "English",

volume = "46",

pages = "3610--3612",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "20",

}

TY - JOUR

T1 - Confirmation by IR of the preferred conformations of CFTA esters in solution

T2 - A highly reliable criterion for the stereochemistry assignment of chiral alcohols

AU - Omata, Kenji

AU - Kotani, Kohsuke

AU - Kabuto, Kuninobu

AU - Fujiwara, Tomoya

AU - Takeuchi, Yoshio

PY - 2010/5/21

Y1 - 2010/5/21

N2 - Direct confirmation of the preferred conformation of diastereomeric esters derived from a chiral secondary alcohol and a chiral derivatizing agent in solution, which is crucial for reliable NMR-based assignment of absolute stereochemistry of the alcohol, has been attained for the first time by examination of IR spectra of the CFTA esters.

AB - Direct confirmation of the preferred conformation of diastereomeric esters derived from a chiral secondary alcohol and a chiral derivatizing agent in solution, which is crucial for reliable NMR-based assignment of absolute stereochemistry of the alcohol, has been attained for the first time by examination of IR spectra of the CFTA esters.

UR - http://www.scopus.com/inward/record.url?scp=77952399715&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77952399715&partnerID=8YFLogxK

U2 - 10.1039/b926793j

DO - 10.1039/b926793j

M3 - Article

C2 - 20393658

AN - SCOPUS:77952399715

SN - 1359-7345

VL - 46

SP - 3610

EP - 3612

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Confirmation by IR of the preferred conformations of CFTA esters in solution: A highly reliable criterion for the stereochemistry assignment of chiral alcohols

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this