Conductive zigzag Pd(iii)-Br chain complex realized by a multiple-hydrogen-bond approach

Mohammad Rasel Mian, Unjila Afrin, Hiroaki Iguchi, Shinya Takaishi, Yoshida Takefumi, Tatsuya Miyamoto, Hiroshi Okamoto, Hisaaki Tanaka, Shin Ichi Kuroda, Masahiro Yamashita

Research output: Contribution to journalArticle

Abstract

Coexistence of zigzag structure and the uncommon Pd(iii) oxidation state in quasi-1D halogen-bridged metal complexes was realized in a conductive Br-bridged Pd chain complex, [Pd(dabdOH)2Br]SO4·3H2O (2), for the first time. Intra- and interchain hydrogen-bond networks among the (2S,3S)-2,3-diaminobutane-1,4-diol (dabdOH) ligand and SO42−and H2O molecules support this unusual structure and electronic state. The electrical conductivity of2reached 0.05 S cm−1at room temperature.

Original languageEnglish
Pages (from-to)3999-4004
Number of pages6
JournalCrystEngComm
Volume22
Issue number23
DOIs
Publication statusPublished - 2020 Jun 21

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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    Mian, M. R., Afrin, U., Iguchi, H., Takaishi, S., Takefumi, Y., Miyamoto, T., Okamoto, H., Tanaka, H., Kuroda, S. I., & Yamashita, M. (2020). Conductive zigzag Pd(iii)-Br chain complex realized by a multiple-hydrogen-bond approach. CrystEngComm, 22(23), 3999-4004. https://doi.org/10.1039/d0ce00332h