Abstract
O-(Alkoxycarbonyl)-N-arylhydroxylamines were efficiently converted to 2-aminophenol derivatives by cationic cobalt catalysts at 30 °C. The results of 18O-labeling experiments suggested that rearrangement of the alkoxycarbonyl group from the aniline nitrogen to the ortho position proceeded in an unprecedented [1,3] manner.
Original language | English |
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Pages (from-to) | 2194-2196 |
Number of pages | 3 |
Journal | Organic letters |
Volume | 19 |
Issue number | 8 |
DOIs | |
Publication status | Published - 2017 Apr 21 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry