Competitive adsorption reaction mechanism of Ni/Yttria-stabilized zirconia cermet anodes in H2-H2O solid oxide fuel cells

Manabu Ihara, Takeshi Kusano, Chiaki Yokoyama

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70 Citations (Scopus)


The reaction mechanism of the most commonly used anode material, Ni/yttria-stabilized zirconia (YSZ) cermets, in H2-H2O solid oxide fuel cells (SOFCs) was investigated. Because the reaction mechanism for the Ni/YSZ anode in H2 has not been conclusively determined, we investigated the detailed dependence of dc polarization and interfacial conductivity of Ni/YSZ cermet anode on the partial pressure of hydrogen (pH2). Based on our experimental results, we developed a model that links the chemical reactions on the anode with the electrical characteristics of the anode such as the dc polarization and the interfacial conductivity. In our model, we assumed competitive adsorption equilibrium of H2, H2O, and O on Ni surfaces at the three-phase boundary, and assumed the rate-determining step to be Langmuir-type reactions of H with O. In SOFCs with Ni/YSZ anodes, reported dependencies of the current and interfacial conductivity on pH and pH2O differ among previous studies. Both our measured dependencies and previously published dependencies were successfully reproduced by our Langmuir reaction model. Furthermore, possible reasons for these different observed dependencies include the different adsorption equilibrium constants.

Original languageEnglish
Pages (from-to)A209-A219
JournalJournal of the Electrochemical Society
Issue number3
Publication statusPublished - 2001 Jan 1

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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