Comparison of the bond lengths for the lanthanide complexes of tripodal heptadentate ligands

Masatoshi Kanesato, Shin Mizukami, Hirohiko Houjou, Hideo Tokuhisa, Emiko Koyama, Yoshinobu Nagawa

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

The preparation and characterization of Ln(III) complexes (Ln=Sm, Yb) of tripodal heptadentate ligand trensal, tris[2-(salicylideneamino)ethyl]amine (H3L1) have been studied. The molecular structures of [LnL1] were determined by X-ray structural analysis; these are heptadentate complexes in which the metal ions are coordinated by the three oxygen atoms and the four nitrogen atoms. [LnL1] is a novel example because the coordination number is seven in the wide range of the series of [LnL1] (Ln=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu). This has made it possible to compare the bond lengths for the lanthanide and yttrium complexes under the same coordination number.

Original languageEnglish
Pages (from-to)307-310
Number of pages4
JournalJournal of Alloys and Compounds
Volume374
Issue number1-2
DOIs
Publication statusPublished - 2004 Jul 14
Externally publishedYes

Keywords

  • Bond lengths for complexes
  • Crystal structures
  • Lanthanide complexes
  • Tripodal ligand
  • Yttrium complexes

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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