Comparison of structures between platinum and palladium complexes of a tetrasilyldisilene

Hisako Hashimoto, Yumiko Sekiguchi, Yohei Sekiguchi, Takeaki Iwamoto, Chizuko Kabuto, Mistuo Kira

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

The first η2-disilene-palladium complexes were synthesized using two different reactions; the reactions of bis(phosphine) dichloropalladiums with a 1,2-dilithiotetrakis(trialkylsilyl)disilane, which was prepared by the reaction of a stable tetrakis(trialkylsilyl)disilene with lithium (Method A) and the direct reactions of the bis(phosphine) dichloropalladiums with the stable disilene (Method B). Comparison of X-ray structural parameters of the disilene-palladium complexes with those of the corresponding platinum complex has indicated that the palladium complex is a metallacycle but its π-complex character is stronger than that of the platinum complex.

Original languageEnglish
Pages (from-to)1241-1245
Number of pages5
JournalCanadian Journal of Chemistry
Volume81
Issue number11
DOIs
Publication statusPublished - 2003 Nov 1

Keywords

  • π-complex
  • Disilene complex
  • Metallacycle
  • Palladium
  • Platinum
  • X-ray structure

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

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