Comparison of corrosion properties of passive films formed on coarse grained and ultrafine grained AISI 2205 duplex stainless steels

Lv Jinlong; Liang Tongxiang; Wang Chen; Dong Limin

doi:10.1016/j.jelechem.2015.09.036

Comparison of corrosion properties of passive films formed on coarse grained and ultrafine grained AISI 2205 duplex stainless steels

Lv Jinlong, Liang Tongxiang, Wang Chen, Dong Limin

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The ultrafine grained 2205 duplex stainless steel with an average grain size of 300 nm was obtained by cold rolling down to 95% reduction in thickness and reversion annealing at 900 °C for 200 s. The ultrafine grained sample showed higher corrosion resistance than coarse grain one in borate buffer solution at room temperature, indicating that the passive film formed on the surface of the ultrafine grained 2205 duplex stainless steel is more protective. Comparing the doping concentrations between coarse grain and ultrafine grained samples from the Mott-Schottky plots, higher corrosion resistance of ultrafine grained sample was probably attributed to lower donor density and the thicker passive film in borate buffer solution. The results of electrochemical impedance spectroscopy were further supported by Raman spectra and XPS analysis.

Original language	English
Pages (from-to)	263-269
Number of pages	7
Journal	Journal of Electroanalytical Chemistry
Volume	757
DOIs	https://doi.org/10.1016/j.jelechem.2015.09.036
Publication status	Published - 2015 Nov 15
Externally published	Yes

Keywords

Defects
Epitaxial growth
Metals
Thin films
X-ray diffraction

ASJC Scopus subject areas

Analytical Chemistry
Chemical Engineering(all)
Electrochemistry

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title = "Comparison of corrosion properties of passive films formed on coarse grained and ultrafine grained AISI 2205 duplex stainless steels",

abstract = "The ultrafine grained 2205 duplex stainless steel with an average grain size of 300 nm was obtained by cold rolling down to 95% reduction in thickness and reversion annealing at 900 °C for 200 s. The ultrafine grained sample showed higher corrosion resistance than coarse grain one in borate buffer solution at room temperature, indicating that the passive film formed on the surface of the ultrafine grained 2205 duplex stainless steel is more protective. Comparing the doping concentrations between coarse grain and ultrafine grained samples from the Mott-Schottky plots, higher corrosion resistance of ultrafine grained sample was probably attributed to lower donor density and the thicker passive film in borate buffer solution. The results of electrochemical impedance spectroscopy were further supported by Raman spectra and XPS analysis.",

keywords = "Defects, Epitaxial growth, Metals, Thin films, X-ray diffraction",

author = "Lv Jinlong and Liang Tongxiang and Wang Chen and Dong Limin",

note = "Funding Information: This work was financially supported by the National Natural Science Foundation of China (Grant No. 91326203 ). Publisher Copyright: {\textcopyright} 2015 Elsevier B.V. All rights reserved. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.",

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day = "15",

doi = "10.1016/j.jelechem.2015.09.036",

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AU - Jinlong, Lv

AU - Tongxiang, Liang

AU - Chen, Wang

AU - Limin, Dong

N1 - Funding Information: This work was financially supported by the National Natural Science Foundation of China (Grant No. 91326203 ). Publisher Copyright: © 2015 Elsevier B.V. All rights reserved. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 2015/11/15

Y1 - 2015/11/15

N2 - The ultrafine grained 2205 duplex stainless steel with an average grain size of 300 nm was obtained by cold rolling down to 95% reduction in thickness and reversion annealing at 900 °C for 200 s. The ultrafine grained sample showed higher corrosion resistance than coarse grain one in borate buffer solution at room temperature, indicating that the passive film formed on the surface of the ultrafine grained 2205 duplex stainless steel is more protective. Comparing the doping concentrations between coarse grain and ultrafine grained samples from the Mott-Schottky plots, higher corrosion resistance of ultrafine grained sample was probably attributed to lower donor density and the thicker passive film in borate buffer solution. The results of electrochemical impedance spectroscopy were further supported by Raman spectra and XPS analysis.

AB - The ultrafine grained 2205 duplex stainless steel with an average grain size of 300 nm was obtained by cold rolling down to 95% reduction in thickness and reversion annealing at 900 °C for 200 s. The ultrafine grained sample showed higher corrosion resistance than coarse grain one in borate buffer solution at room temperature, indicating that the passive film formed on the surface of the ultrafine grained 2205 duplex stainless steel is more protective. Comparing the doping concentrations between coarse grain and ultrafine grained samples from the Mott-Schottky plots, higher corrosion resistance of ultrafine grained sample was probably attributed to lower donor density and the thicker passive film in borate buffer solution. The results of electrochemical impedance spectroscopy were further supported by Raman spectra and XPS analysis.

KW - Defects

KW - Epitaxial growth

KW - Metals

KW - Thin films

KW - X-ray diffraction

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JO - Journal of Electroanalytical Chemistry

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SN - 1572-6657

ER -

Comparison of corrosion properties of passive films formed on coarse grained and ultrafine grained AISI 2205 duplex stainless steels

Abstract

Keywords

ASJC Scopus subject areas

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