Comparison between DySc2N@C80 and Dy2ScN@C80 single-molecule magnetic metallofullerenes encapsulated in single-wall carbon nanotubes

Satoshi Ito, Ryo Nakanishi, Keiichi Katoh, Brian K. Breedlove, Tetsu Sato, Zhao Yang Li, Yoji Horii, Masanori Wakizaka, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

Abstract

Encapsulation of a metallofullerene single-molecule magnet, Dy2ScN@C80, into single-wall carbon nanotubes (SWCNTs) accelerates magnetic relaxation processes. In contrast, encapsulation of DySc2N@C80 suppresses them. The effects of the encapsulation are discussed in terms of intermolecular magnetic interactions and charge transfer among metallofullerenes and SWCNTs.

Original languageEnglish
JournalDalton Transactions
DOIs
Publication statusAccepted/In press - 2022

ASJC Scopus subject areas

  • Inorganic Chemistry

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