TY - JOUR
T1 - Combinatorial laser MBE synthesis of 3d ion doped epitaxial ZnO thin films
AU - Jin, Zhengwu W.
AU - Murakami, M.
AU - Fukumura, T.
AU - Matsumoto, Y.
AU - Ohtomo, A.
AU - Kawasaki, M.
AU - Koinuma, H.
N1 - Funding Information:
This work was supported by Proposal Based Program of NEDO (99S12010) and JSPS Research for the Future Program in the area of Atomic-Scale Surface and Interface Dynamics (RFTF96P00205).
PY - 2000/6/2
Y1 - 2000/6/2
N2 - Combinatorial laser MBE (CLMBE) method was employed to fabricate epitaxial ZnO thin films doped with all the 3d transition metal ions. The solubility behavior of 3d ions was studied from the viewpoints of ionic radius and valence state. Transmission spectra were classified into four groups with respect to the absorption edge shifts and d-d electron transitions. Mn2+ and Co2+ ions show very high solubility limits among all the 3d ion species and have high spin electron configurations in ZnO matrix. Such a high throughput synthesis tool as CLMBE is shown to be a powerful tool for exploring novel functionality of thin film materials.
AB - Combinatorial laser MBE (CLMBE) method was employed to fabricate epitaxial ZnO thin films doped with all the 3d transition metal ions. The solubility behavior of 3d ions was studied from the viewpoints of ionic radius and valence state. Transmission spectra were classified into four groups with respect to the absorption edge shifts and d-d electron transitions. Mn2+ and Co2+ ions show very high solubility limits among all the 3d ion species and have high spin electron configurations in ZnO matrix. Such a high throughput synthesis tool as CLMBE is shown to be a powerful tool for exploring novel functionality of thin film materials.
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U2 - 10.1016/S0022-0248(00)00058-0
DO - 10.1016/S0022-0248(00)00058-0
M3 - Conference article
AN - SCOPUS:0033701538
VL - 214
SP - 55
EP - 58
JO - Journal of Crystal Growth
JF - Journal of Crystal Growth
SN - 0022-0248
T2 - The 9th International Conference on II-VI Compounds
Y2 - 1 November 1999 through 5 November 1999
ER -