Abstract
We show the synthetic procedure of colored magnetic films composed of Prussian blue analog-based magnets and their magneto-optical effects in the visible region. Magnetic thin films of M3II[CrIII(CN)6]2·zH2O (M = Co, Ni, Cu) are prepared on transparent Nafion membrane by an ion-exchange process and these films exhibit Faraday effect due to d-d transition of MII. The film-type of (FexICr1-xII)3[CrIII(CN)6]2·15H2O is electrochemically prepared by reducing aqueous solutions containing three compounds of K 3[Cr(CN)6], CrCl3, and FeCl3. These films display magnetization-induced second harmonic generation below Curie temperature.
Original language | English |
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Pages (from-to) | 2901-2905 |
Number of pages | 5 |
Journal | Polyhedron |
Volume | 24 |
Issue number | 16-17 |
DOIs | |
Publication status | Published - 2005 Nov 17 |
Externally published | Yes |
Keywords
- Cyano-briged metal assemblies
- Magnetic thin films
- Magnetization-induced second harmonic generation
- Magneto-optical effect
- Prussian blue analogs
- Second harmonic generation
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry