Colored magnetic films composed of cyano-bridged metal assemblies and magneto-optical functionalities

Tomohiro Nuida; Toshiya Hozumi; Wataru Kosaka; Shunsuke Sakurai; Satoru Ikeda; Tomoyuki Matsuda; Hiroko Tokoro; Kazuhito Hashimoto; Shin Ichi Ohkoshi

doi:10.1016/j.poly.2005.08.023

Colored magnetic films composed of cyano-bridged metal assemblies and magneto-optical functionalities

Tomohiro Nuida, Toshiya Hozumi, Wataru Kosaka, Shunsuke Sakurai, Satoru Ikeda, Tomoyuki Matsuda, Hiroko Tokoro, Kazuhito Hashimoto, Shin Ichi Ohkoshi

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

We show the synthetic procedure of colored magnetic films composed of Prussian blue analog-based magnets and their magneto-optical effects in the visible region. Magnetic thin films of M3II[CrIII(CN)6]2·zH2O (M = Co, Ni, Cu) are prepared on transparent Nafion membrane by an ion-exchange process and these films exhibit Faraday effect due to d-d transition of M^II. The film-type of (FexICr1-xII)3[CrIII(CN)6]2·15H2O is electrochemically prepared by reducing aqueous solutions containing three compounds of K ₃[Cr(CN)₆], CrCl₃, and FeCl₃. These films display magnetization-induced second harmonic generation below Curie temperature.

Original language	English
Pages (from-to)	2901-2905
Number of pages	5
Journal	Polyhedron
Volume	24
Issue number	16-17
DOIs	https://doi.org/10.1016/j.poly.2005.08.023
Publication status	Published - 2005 Nov 17
Externally published	Yes

Keywords

Cyano-briged metal assemblies
Magnetic thin films
Magnetization-induced second harmonic generation
Magneto-optical effect
Prussian blue analogs
Second harmonic generation

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.poly.2005.08.023

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Colored magnetic films composed of cyano-bridged metal assemblies and magneto-optical functionalities. / Nuida, Tomohiro; Hozumi, Toshiya; Kosaka, Wataru; Sakurai, Shunsuke; Ikeda, Satoru; Matsuda, Tomoyuki; Tokoro, Hiroko; Hashimoto, Kazuhito; Ohkoshi, Shin Ichi.

In: Polyhedron, Vol. 24, No. 16-17, 17.11.2005, p. 2901-2905.

Research output: Contribution to journal › Article › peer-review

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title = "Colored magnetic films composed of cyano-bridged metal assemblies and magneto-optical functionalities",

abstract = "We show the synthetic procedure of colored magnetic films composed of Prussian blue analog-based magnets and their magneto-optical effects in the visible region. Magnetic thin films of M3II[CrIII(CN)6]2·zH2O (M = Co, Ni, Cu) are prepared on transparent Nafion membrane by an ion-exchange process and these films exhibit Faraday effect due to d-d transition of MII. The film-type of (FexICr1-xII)3[CrIII(CN)6]2·15H2O is electrochemically prepared by reducing aqueous solutions containing three compounds of K 3[Cr(CN)6], CrCl3, and FeCl3. These films display magnetization-induced second harmonic generation below Curie temperature.",

keywords = "Cyano-briged metal assemblies, Magnetic thin films, Magnetization-induced second harmonic generation, Magneto-optical effect, Prussian blue analogs, Second harmonic generation",

author = "Tomohiro Nuida and Toshiya Hozumi and Wataru Kosaka and Shunsuke Sakurai and Satoru Ikeda and Tomoyuki Matsuda and Hiroko Tokoro and Kazuhito Hashimoto and Ohkoshi, {Shin Ichi}",

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AU - Nuida, Tomohiro

AU - Hozumi, Toshiya

AU - Kosaka, Wataru

AU - Sakurai, Shunsuke

AU - Ikeda, Satoru

AU - Matsuda, Tomoyuki

AU - Tokoro, Hiroko

AU - Hashimoto, Kazuhito

AU - Ohkoshi, Shin Ichi

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N2 - We show the synthetic procedure of colored magnetic films composed of Prussian blue analog-based magnets and their magneto-optical effects in the visible region. Magnetic thin films of M3II[CrIII(CN)6]2·zH2O (M = Co, Ni, Cu) are prepared on transparent Nafion membrane by an ion-exchange process and these films exhibit Faraday effect due to d-d transition of MII. The film-type of (FexICr1-xII)3[CrIII(CN)6]2·15H2O is electrochemically prepared by reducing aqueous solutions containing three compounds of K 3[Cr(CN)6], CrCl3, and FeCl3. These films display magnetization-induced second harmonic generation below Curie temperature.

AB - We show the synthetic procedure of colored magnetic films composed of Prussian blue analog-based magnets and their magneto-optical effects in the visible region. Magnetic thin films of M3II[CrIII(CN)6]2·zH2O (M = Co, Ni, Cu) are prepared on transparent Nafion membrane by an ion-exchange process and these films exhibit Faraday effect due to d-d transition of MII. The film-type of (FexICr1-xII)3[CrIII(CN)6]2·15H2O is electrochemically prepared by reducing aqueous solutions containing three compounds of K 3[Cr(CN)6], CrCl3, and FeCl3. These films display magnetization-induced second harmonic generation below Curie temperature.

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KW - Magnetic thin films

KW - Magnetization-induced second harmonic generation

KW - Magneto-optical effect

KW - Prussian blue analogs

KW - Second harmonic generation

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