Colored magnetic films composed of cyano-bridged metal assemblies and magneto-optical functionalities

Tomohiro Nuida, Toshiya Hozumi, Wataru Kosaka, Shunsuke Sakurai, Satoru Ikeda, Tomoyuki Matsuda, Hiroko Tokoro, Kazuhito Hashimoto, Shin Ichi Ohkoshi

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

We show the synthetic procedure of colored magnetic films composed of Prussian blue analog-based magnets and their magneto-optical effects in the visible region. Magnetic thin films of M3II[CrIII(CN)6]2·zH2O (M = Co, Ni, Cu) are prepared on transparent Nafion membrane by an ion-exchange process and these films exhibit Faraday effect due to d-d transition of MII. The film-type of (FexICr1-xII)3[CrIII(CN)6]2·15H2O is electrochemically prepared by reducing aqueous solutions containing three compounds of K 3[Cr(CN)6], CrCl3, and FeCl3. These films display magnetization-induced second harmonic generation below Curie temperature.

Original languageEnglish
Pages (from-to)2901-2905
Number of pages5
JournalPolyhedron
Volume24
Issue number16-17
DOIs
Publication statusPublished - 2005 Nov 17
Externally publishedYes

Keywords

  • Cyano-briged metal assemblies
  • Magnetic thin films
  • Magnetization-induced second harmonic generation
  • Magneto-optical effect
  • Prussian blue analogs
  • Second harmonic generation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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