TY - JOUR
T1 - Colored magnetic films composed of cyano-bridged metal assemblies and magneto-optical functionalities
AU - Nuida, Tomohiro
AU - Hozumi, Toshiya
AU - Kosaka, Wataru
AU - Sakurai, Shunsuke
AU - Ikeda, Satoru
AU - Matsuda, Tomoyuki
AU - Tokoro, Hiroko
AU - Hashimoto, Kazuhito
AU - Ohkoshi, Shin Ichi
N1 - Funding Information:
We thank Prof. M. Verdagure, Dr. M.M. Matsushita, and Prof. N. Kojima. The present research is supported in part by a Grant for 21st Century COE Program “Human-Friendly Materials based on Chemistry” and a Grand-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology of Japan.
PY - 2005/11/17
Y1 - 2005/11/17
N2 - We show the synthetic procedure of colored magnetic films composed of Prussian blue analog-based magnets and their magneto-optical effects in the visible region. Magnetic thin films of M3II[CrIII(CN)6]2·zH2O (M = Co, Ni, Cu) are prepared on transparent Nafion membrane by an ion-exchange process and these films exhibit Faraday effect due to d-d transition of MII. The film-type of (FexICr1-xII)3[CrIII(CN)6]2·15H2O is electrochemically prepared by reducing aqueous solutions containing three compounds of K 3[Cr(CN)6], CrCl3, and FeCl3. These films display magnetization-induced second harmonic generation below Curie temperature.
AB - We show the synthetic procedure of colored magnetic films composed of Prussian blue analog-based magnets and their magneto-optical effects in the visible region. Magnetic thin films of M3II[CrIII(CN)6]2·zH2O (M = Co, Ni, Cu) are prepared on transparent Nafion membrane by an ion-exchange process and these films exhibit Faraday effect due to d-d transition of MII. The film-type of (FexICr1-xII)3[CrIII(CN)6]2·15H2O is electrochemically prepared by reducing aqueous solutions containing three compounds of K 3[Cr(CN)6], CrCl3, and FeCl3. These films display magnetization-induced second harmonic generation below Curie temperature.
KW - Cyano-briged metal assemblies
KW - Magnetic thin films
KW - Magnetization-induced second harmonic generation
KW - Magneto-optical effect
KW - Prussian blue analogs
KW - Second harmonic generation
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U2 - 10.1016/j.poly.2005.08.023
DO - 10.1016/j.poly.2005.08.023
M3 - Article
AN - SCOPUS:27644500529
VL - 24
SP - 2901
EP - 2905
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 16-17
ER -