Collision-energy-resolved Penning ionization electron spectroscopy of substituted ethylenes

Naoki Kishimoto; Takeo Oda; Koichi Ohno

doi:10.1016/j.elspec.2004.02.066

Collision-energy-resolved Penning ionization electron spectroscopy of substituted ethylenes

Naoki Kishimoto, Takeo Oda, Koichi Ohno

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Collision-energy-resolved Penning ionization electron spectra of NH ₂CH₂CH₂CN and HOCH₂CH₂CN by He^*(2³S) metastable atoms were observed. Ionization from orbitals extending around CN groups shows large intensity, negative collision energy dependence of partial ionization cross sections (CEDPICS) and negative peak energy shift with respect to the estimated peak positions at ionization energies, and attractive interactions around the nitrile group were obtained by model potential energy calculations. Attractive interactions around NH₂ and OH groups also result in negative CEDPICS and negative peak energy shift. Observed bands in photoelectron spectrum and Penning ionization electron spectrum of NH₂CH₂CH ₂CN can be ascribed to ionization from two conformers as calculated by a theoretical method.

Original language	English
Pages (from-to)	319-324
Number of pages	6
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	137-140
Issue number	SPEC. ISS.
DOIs	https://doi.org/10.1016/j.elspec.2004.02.066
Publication status	Published - 2004 Jul

Keywords

Collision energy
Interaction potential
Partial ionization cross section
Penning ionization electron spectrum

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Radiation
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

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10.1016/j.elspec.2004.02.066

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@article{50747dd59ca14cab8db8d08abf1ee633,

title = "Collision-energy-resolved Penning ionization electron spectroscopy of substituted ethylenes",

abstract = "Collision-energy-resolved Penning ionization electron spectra of NH 2CH2CH2CN and HOCH2CH2CN by He*(23S) metastable atoms were observed. Ionization from orbitals extending around CN groups shows large intensity, negative collision energy dependence of partial ionization cross sections (CEDPICS) and negative peak energy shift with respect to the estimated peak positions at ionization energies, and attractive interactions around the nitrile group were obtained by model potential energy calculations. Attractive interactions around NH2 and OH groups also result in negative CEDPICS and negative peak energy shift. Observed bands in photoelectron spectrum and Penning ionization electron spectrum of NH2CH2CH 2CN can be ascribed to ionization from two conformers as calculated by a theoretical method.",

keywords = "Collision energy, Interaction potential, Partial ionization cross section, Penning ionization electron spectrum",

author = "Naoki Kishimoto and Takeo Oda and Koichi Ohno",

note = "Funding Information: This work has been supported by a Grant in Aid for Scientific Research from the Japanese Ministry of Education, Culture, Sports, Science and Technology.",

year = "2004",

month = jul,

doi = "10.1016/j.elspec.2004.02.066",

language = "English",

volume = "137-140",

pages = "319--324",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier",

number = "SPEC. ISS.",

}

TY - JOUR

T1 - Collision-energy-resolved Penning ionization electron spectroscopy of substituted ethylenes

AU - Kishimoto, Naoki

AU - Oda, Takeo

AU - Ohno, Koichi

N1 - Funding Information: This work has been supported by a Grant in Aid for Scientific Research from the Japanese Ministry of Education, Culture, Sports, Science and Technology.

PY - 2004/7

Y1 - 2004/7

N2 - Collision-energy-resolved Penning ionization electron spectra of NH 2CH2CH2CN and HOCH2CH2CN by He*(23S) metastable atoms were observed. Ionization from orbitals extending around CN groups shows large intensity, negative collision energy dependence of partial ionization cross sections (CEDPICS) and negative peak energy shift with respect to the estimated peak positions at ionization energies, and attractive interactions around the nitrile group were obtained by model potential energy calculations. Attractive interactions around NH2 and OH groups also result in negative CEDPICS and negative peak energy shift. Observed bands in photoelectron spectrum and Penning ionization electron spectrum of NH2CH2CH 2CN can be ascribed to ionization from two conformers as calculated by a theoretical method.

AB - Collision-energy-resolved Penning ionization electron spectra of NH 2CH2CH2CN and HOCH2CH2CN by He*(23S) metastable atoms were observed. Ionization from orbitals extending around CN groups shows large intensity, negative collision energy dependence of partial ionization cross sections (CEDPICS) and negative peak energy shift with respect to the estimated peak positions at ionization energies, and attractive interactions around the nitrile group were obtained by model potential energy calculations. Attractive interactions around NH2 and OH groups also result in negative CEDPICS and negative peak energy shift. Observed bands in photoelectron spectrum and Penning ionization electron spectrum of NH2CH2CH 2CN can be ascribed to ionization from two conformers as calculated by a theoretical method.

KW - Collision energy

KW - Interaction potential

KW - Partial ionization cross section

KW - Penning ionization electron spectrum

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U2 - 10.1016/j.elspec.2004.02.066

DO - 10.1016/j.elspec.2004.02.066

M3 - Article

AN - SCOPUS:2942534838

SN - 0368-2048

VL - 137-140

SP - 319

EP - 324

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

IS - SPEC. ISS.

ER -

Collision-energy-resolved Penning ionization electron spectroscopy of substituted ethylenes

Abstract

Keywords

ASJC Scopus subject areas

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