Coherent transfer via environment-induced vibronic resonance

Hiroyuki Tamura

    Research output: Contribution to journalArticlepeer-review

    7 Citations (Scopus)

    Abstract

    We systematically analyze vibronic dynamics considering a high-frequency system mode and low-frequency environmental modes by using quantum dynamics calculations. We demonstrate how the vibronic resonance and environment dynamics induce a coherent transfer between coupled electronic states with a potential energy bias. The concerted dynamics of the low-frequency modes modulates the potential crossing, thereby inducing a coherent population transfer when the resonance condition is matched. This feature would underlie transfer phenomena in certain realistic systems.

    Original languageEnglish
    Article number214705
    JournalJournal of Chemical Physics
    Volume130
    Issue number21
    DOIs
    Publication statusPublished - 2009

    ASJC Scopus subject areas

    • Physics and Astronomy(all)
    • Physical and Theoretical Chemistry

    Fingerprint Dive into the research topics of 'Coherent transfer via environment-induced vibronic resonance'. Together they form a unique fingerprint.

    Cite this