Cobalt-catalyzed preparation of arylindium reagents from aryl and heteroaryl bromides

Laksmikanta Adak, Naohiko Yoshikai

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)

Abstract

A cobalt-bathophenanthroline catalyst has been developed for the direct preparation of a variety of arylindium reagents from the corresponding aryl and heteroaryl bromides in the presence of indium metal and lithium chloride. The thus-formed arylindium reagents undergo efficient palladium-catalyzed cross-coupling reactions with aryl iodides, tolerating various functional groups including hydroxy and free amino groups.

Original languageEnglish
Pages (from-to)7563-7568
Number of pages6
JournalJournal of Organic Chemistry
Volume76
Issue number18
DOIs
Publication statusPublished - 2011 Sep 16
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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