Cobalt-Catalyzed, N-H Imine-Directed Arene C-H Benzylation with Benzyl Phosphates

Roshayed Ali Laskar, Naohiko Yoshikai

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A cobalt-catalyzed ortho-C-H benzylation reaction of pivalophenone N-H imines with benzyl phosphates is reported. The reaction is promoted at room temperature by a ternary catalytic system comprising Co(acac)3, a pyridylphosphine ligand, and a Grignard reagent and tolerates a series of substituted pivalophenone imines and benzyl phosphates to afford various diarylmethane derivatives in moderate yields.

Original languageEnglish
Pages (from-to)13172-13178
Number of pages7
JournalJournal of Organic Chemistry
Volume84
Issue number20
DOIs
Publication statusPublished - 2019 Oct 18
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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