Cobalt-catalyzed directed C-H alkenylation of pivalophenone N-H imine with alkenyl phosphates

Wengang Xu, Naohiko Yoshikai

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

A cobalt-N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C-H alkenylation reaction of pivalophenone N-H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N-H imines as well as cyclic and acyclic alkenyl phosphates.

Original languageEnglish
Pages (from-to)709-715
Number of pages7
JournalBeilstein Journal of Organic Chemistry
Volume14
DOIs
Publication statusPublished - 2018 Mar 28
Externally publishedYes

Keywords

  • Alkenylation
  • C-C bond formation
  • C-H activation
  • Cobalt
  • Imine

ASJC Scopus subject areas

  • Organic Chemistry

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