Cobalt antiferromagnetic ring and grid single-molecule magnet

Takuya Shiga, Takuto Matsumoto, Mao Noguchi, Tatsuya Onuki, Norihisa Hoshino, Graham N. Newton, Motohiro Nakano, Hiroki Oshio

Research output: Contribution to journalArticlepeer-review

39 Citations (Scopus)

Abstract

Grid magnet: A Co8 ring and a Co9 grid complex are synthesized using a multidentate polypyridine-type ligand and are shown to exhibit all antiferro-magnetic interactions between metal Grid magnet: A Co8 ring and a Co9 grid complex are synthesized using a multidentate polypyridine-type ligand and are shown to exhibit all antiferro-magnetic interactions between metal centers, with the grid complex displaying SMM properties as a result of alternating high spin/low spin metal centers in the outer 8-membered ring.

Original languageEnglish
Pages (from-to)1660-1663
Number of pages4
JournalChemistry - An Asian Journal
Volume4
Issue number11
DOIs
Publication statusPublished - 2009 Nov 2
Externally publishedYes

Keywords

  • Antiferromagnetic ring
  • Cobalt
  • Grid complex
  • Self-assembly
  • Single-molecule magnet

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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