Coating of CaTiO3 on titanium substrates by hydrothermal reactions using calcium-ethylene diamine tetra acetic acid chelate

Y. Fujishiro, N. Sato, S. Uchida, T. Sato

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    34 Citations (Scopus)

    Abstract

    Titanium plates were treated in [Ti(O2)EDTA]2--Ca(EDTA)2- mixed solutions and/or Ca(EDTA)2- solutions (where EDTA is ethylene diamine tetra acetic acid) at pH 9-13 and 150-250°C for 0.5-12 h. The film, about 50 μm thick, and consisting of mixtures of CaTiO3 and TiO2 was formed in 0.01 M [Ti(O2)EDTA]2--O.O1 M Ca(EDTA)2- mixed solution at pH 13 and 250°C for 6 h. The film consisted of large icosahedral and hexagonal particles, of about 10 μm diameter, and small aggregated particles, of about 1 μm diameter. On the other hand, the film, about 20 μm thick, consisted of hexagonal plate-like CaTiO3 particles, of about 1 μm diameter, was formed in 0.01 M Ca(EDTA)2- solution at pH 13 and 250°C for 6 h. The thickness of both films increased with time, where the film formation rate in 0.01 M [Ti(O2)EDTA]2--0.01 M Ca(EDTA)2- mixed solution was much faster. The CaTiO3 film formed on the surface of titanium promoted the precipitation of hydroxyapatite on the substrate by the hydrothermal reactions in Ca(EDTA)2--PO43- mixed solutions.

    Original languageEnglish
    Pages (from-to)363-367
    Number of pages5
    JournalJournal of Materials Science: Materials in Medicine
    Volume9
    Issue number7
    DOIs
    Publication statusPublished - 1998 Jul 1

    ASJC Scopus subject areas

    • Biophysics
    • Bioengineering
    • Biomaterials
    • Biomedical Engineering

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