cis and trans forms of a binuclear subphthalocyanine

Takamitsu Fukuda; Jay R. Stork; Richard J. Potucek; Marilyn M. Olmstead; Bruce C. Noll; Nagao Kobayashi; William S. Durfee

doi:10.1002/1521-3773(20020715)41:14<2565::AID-ANIE2565>3.0.CO;2-G

cis and trans forms of a binuclear subphthalocyanine

Takamitsu Fukuda, Jay R. Stork, Richard J. Potucek, Marilyn M. Olmstead, Bruce C. Noll, Nagao Kobayashi, William S. Durfee

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

The structures of cis and trans forms of a binuclear subphthalocyanine (SubPc) have been determined by X-ray crystallography (see pictures). Electronic absorption and magnetic circular dichrosim spectra of these dimers are similar in shape, but the Q band of the trans isomer appears at longer wavelength than that of the cis isomer by about 3-4 nm.

Original language	English
Pages (from-to)	2565-2568
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	14
DOIs	https://doi.org/10.1002/1521-3773(20020715)41:14<2565::AID-ANIE2565>3.0.CO;2-G
Publication status	Published - 2002 Jul 15
Externally published	Yes

Keywords

Boron
Electronic spectroscopy
Macrocycles
Phthalocyanines
Structure elucidation

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/1521-3773(20020715)41:14<2565::AID-ANIE2565>3.0.CO;2-G

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abstract = "The structures of cis and trans forms of a binuclear subphthalocyanine (SubPc) have been determined by X-ray crystallography (see pictures). Electronic absorption and magnetic circular dichrosim spectra of these dimers are similar in shape, but the Q band of the trans isomer appears at longer wavelength than that of the cis isomer by about 3-4 nm.",

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AU - Fukuda, Takamitsu

AU - Stork, Jay R.

AU - Potucek, Richard J.

AU - Olmstead, Marilyn M.

AU - Noll, Bruce C.

AU - Kobayashi, Nagao

AU - Durfee, William S.

PY - 2002/7/15

Y1 - 2002/7/15

N2 - The structures of cis and trans forms of a binuclear subphthalocyanine (SubPc) have been determined by X-ray crystallography (see pictures). Electronic absorption and magnetic circular dichrosim spectra of these dimers are similar in shape, but the Q band of the trans isomer appears at longer wavelength than that of the cis isomer by about 3-4 nm.

AB - The structures of cis and trans forms of a binuclear subphthalocyanine (SubPc) have been determined by X-ray crystallography (see pictures). Electronic absorption and magnetic circular dichrosim spectra of these dimers are similar in shape, but the Q band of the trans isomer appears at longer wavelength than that of the cis isomer by about 3-4 nm.

KW - Boron

KW - Electronic spectroscopy

KW - Macrocycles

KW - Phthalocyanines

KW - Structure elucidation

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cis and trans forms of a binuclear subphthalocyanine

Abstract

Keywords

ASJC Scopus subject areas

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