Chirality Control and Its Memory at Microphase-Separated Interface of Self-Assembled Chiral Block Copolymers for Nanostructured Chiral Materials

Ming Chia Li, Naoki Ousaka, Hsiao Fang Wang, Eiji Yashima, Rong Ming Ho

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Here, we show the induced chirality of an achiral chromophoric dye as a joint of polylactide-containing chiral block copolymers (BCPs∗) driven by self-assembly, giving the achiral dyes preferentially arranged in a one-handed helical array at the microphase-separated interface. This helical arrangement of the achiral dyes can be "memorized" after hydrolysis of the polylactides in the BCPs∗ and serves as a chiral template for further chirality induction of different achiral dyes, probably through attractive aromatic π-π interactions at the interface, producing nanostructured chiral materials with tunable circular dichroism signals at desired wavelengths.

Original languageEnglish
Pages (from-to)980-986
Number of pages7
JournalACS Macro Letters
Volume6
Issue number9
DOIs
Publication statusPublished - 2017 Sep 19
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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