Chiral recognition of tetrahelicene dicarboxylic acid by linear dextrins

Koji Kano; Shigeru Negi; Ryoko Takaoka; Hisanobu Kamo; Takashi Kitae; Masahiko Yamaguchi; Hitoshi Okubo; Masahiro Hirama

doi:10.1246/cl.1997.715

Chiral recognition of tetrahelicene dicarboxylic acid by linear dextrins

Koji Kano, Shigeru Negi, Ryoko Takaoka, Hisanobu Kamo, Takashi Kitae, Masahiko Yamaguchi, Hitoshi Okubo, Masahiro Hirama

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Recognition of the helicity of 1,12-dimethylbenzo[c]phenanthrene-5,8-dicarboxylic acid (1) by linear oligosaccharides has been studied by ¹H NMR spectroscopy and capillary zone electrophoresis. Both methods clearly indicate that maltotetraose, maltopentaose, maltohexaose, and maltoheptaose selectively complex with the (M)-isomer of 1 as a guest through hydrogen-bonding interaction in water.

Original language	English
Pages (from-to)	715-716
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.1997.715
Publication status	Published - 1997

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Recognition of the helicity of 1,12-dimethylbenzo[c]phenanthrene-5,8-dicarboxylic acid (1) by linear oligosaccharides has been studied by 1H NMR spectroscopy and capillary zone electrophoresis. Both methods clearly indicate that maltotetraose, maltopentaose, maltohexaose, and maltoheptaose selectively complex with the (M)-isomer of 1 as a guest through hydrogen-bonding interaction in water.",

author = "Koji Kano and Shigeru Negi and Ryoko Takaoka and Hisanobu Kamo and Takashi Kitae and Masahiko Yamaguchi and Hitoshi Okubo and Masahiro Hirama",

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journal = "Chemistry Letters",

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T1 - Chiral recognition of tetrahelicene dicarboxylic acid by linear dextrins

AU - Kano, Koji

AU - Negi, Shigeru

AU - Takaoka, Ryoko

AU - Kamo, Hisanobu

AU - Kitae, Takashi

AU - Yamaguchi, Masahiko

AU - Okubo, Hitoshi

AU - Hirama, Masahiro

PY - 1997

Y1 - 1997

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AB - Recognition of the helicity of 1,12-dimethylbenzo[c]phenanthrene-5,8-dicarboxylic acid (1) by linear oligosaccharides has been studied by 1H NMR spectroscopy and capillary zone electrophoresis. Both methods clearly indicate that maltotetraose, maltopentaose, maltohexaose, and maltoheptaose selectively complex with the (M)-isomer of 1 as a guest through hydrogen-bonding interaction in water.

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JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

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