Chiral recognition of tetrahelicene dicarboxylic acid by linear dextrins

Koji Kano, Shigeru Negi, Ryoko Takaoka, Hisanobu Kamo, Takashi Kitae, Masahiko Yamaguchi, Hitoshi Okubo, Masahiro Hirama

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

Recognition of the helicity of 1,12-dimethylbenzo[c]phenanthrene-5,8-dicarboxylic acid (1) by linear oligosaccharides has been studied by 1H NMR spectroscopy and capillary zone electrophoresis. Both methods clearly indicate that maltotetraose, maltopentaose, maltohexaose, and maltoheptaose selectively complex with the (M)-isomer of 1 as a guest through hydrogen-bonding interaction in water.

Original languageEnglish
Pages (from-to)715-716
Number of pages2
JournalChemistry Letters
Issue number8
DOIs
Publication statusPublished - 1997

ASJC Scopus subject areas

  • Chemistry(all)

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