TY - GEN
T1 - Chiral electrode behaviors of magnetoelectrodeposited Ag films for amino acids
AU - Mogi, I.
PY - 2008/12/1
Y1 - 2008/12/1
N2 - Chiral aspects were investigated in the Ag films electrodeposited under magnetic fields of 2 and 3 T perpendicular to the electrode surface. The films were used as modified electrodes, and cyclic voltammograms were examined for the electrochemical oxidation of cysteine and histidine. In both cases, the chiral aspects were observed as the peak current difference between the enantiomers, and the chirality depended on the polarity of the magnetic field during the electrodeposition. The formation of such chiral films is discussed in connection with the micro-MHD effect.
AB - Chiral aspects were investigated in the Ag films electrodeposited under magnetic fields of 2 and 3 T perpendicular to the electrode surface. The films were used as modified electrodes, and cyclic voltammograms were examined for the electrochemical oxidation of cysteine and histidine. In both cases, the chiral aspects were observed as the peak current difference between the enantiomers, and the chirality depended on the polarity of the magnetic field during the electrodeposition. The formation of such chiral films is discussed in connection with the micro-MHD effect.
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U2 - 10.1149/1.3000680
DO - 10.1149/1.3000680
M3 - Conference contribution
AN - SCOPUS:70349452302
SN - 9781605606545
T3 - ECS Transactions
SP - 45
EP - 52
BT - ECS Transactions - Exploiting Magnets and Magnetic Fields in Electrochemical Systems and Devices
T2 - Exploiting Magnets and Magnetic Fields in Electrochemical Systems and Devices - 213th Meeting of the Electrochemical Society
Y2 - 18 May 2008 through 23 May 2008
ER -