Chemoselective reduction of α,β-unsaturated aldehydes using an unsupported nanoporous gold catalyst

Balaram S. Takale; Shanqiang Wang; Xuan Zhang; Xiujuan Feng; Xiaoqiang Yu; Tienan Jin; Ming Bao; Yoshinori Yamamoto

doi:10.1039/c4cc07068b

Chemoselective reduction of α,β-unsaturated aldehydes using an unsupported nanoporous gold catalyst

Balaram S. Takale, Shanqiang Wang, Xuan Zhang, Xiujuan Feng, Xiaoqiang Yu, Tienan Jin, Ming Bao, Yoshinori Yamamoto

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

The remarkable effect of an unsupported nanoporous gold catalyst (AuNPore) on chemoselective hydrogenation of α,β-unsaturated aldehydes using silane has been described. Enals can be reduced with excellent selectivity, giving the corresponding allylic alcohols in good to high chemical yields.

Original language	English
Pages (from-to)	14401-14404
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	92
DOIs	https://doi.org/10.1039/c4cc07068b
Publication status	Published - 2014 Oct 23

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The remarkable effect of an unsupported nanoporous gold catalyst (AuNPore) on chemoselective hydrogenation of α,β-unsaturated aldehydes using silane has been described. Enals can be reduced with excellent selectivity, giving the corresponding allylic alcohols in good to high chemical yields.",

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AU - Takale, Balaram S.

AU - Wang, Shanqiang

AU - Zhang, Xuan

AU - Feng, Xiujuan

AU - Yu, Xiaoqiang

AU - Jin, Tienan

AU - Bao, Ming

AU - Yamamoto, Yoshinori

PY - 2014/10/23

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AB - The remarkable effect of an unsupported nanoporous gold catalyst (AuNPore) on chemoselective hydrogenation of α,β-unsaturated aldehydes using silane has been described. Enals can be reduced with excellent selectivity, giving the corresponding allylic alcohols in good to high chemical yields.

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Chemoselective reduction of α,β-unsaturated aldehydes using an unsupported nanoporous gold catalyst

Abstract

ASJC Scopus subject areas

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