Chemical trend of Ln-M exchange couplings in heterometallic complexes with Ln = Gd, Tb, Dy, Ho, Er and M = Cu, V

Ryo Watanabe, Kei Fujiwara, Atsushi Okazawa, Go Tanaka, Shunsuke Yoshii, Hiroyuki Nojiri, Takayuki Ishida

Research output: Contribution to journalArticlepeer-review

37 Citations (Scopus)

Abstract

The 4f-3d exchange couplings were definitively and precisely determined in the dinuclear complexes (Ln-M) involving double μ-oxo-bridges, by means of combined high-frequency electron paramagnetic resonance and pulsed-field magnetization techniques, revealing a monotonic decrease of ferromagnetic JLn-Cu in the order of the atomic number, 64Gd to 68Er.

Original languageEnglish
Pages (from-to)2110-2112
Number of pages3
JournalChemical Communications
Volume47
Issue number7
DOIs
Publication statusPublished - 2011 Feb 1

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Chemical trend of Ln-M exchange couplings in heterometallic complexes with Ln = Gd, Tb, Dy, Ho, Er and M = Cu, V'. Together they form a unique fingerprint.

Cite this