Chemical thermodynamic stabilities of electrode/electrolyte interfaces of high temperature electrochemical cells

Harumi Yokokawa; Teruhisa Horita; Natsuko Sakai; Tatsuya Kawada; Masayuki Dokiya

doi:10.1016/0167-2738(95)00092-K

Chemical thermodynamic stabilities of electrode/electrolyte interfaces of high temperature electrochemical cells

Harumi Yokokawa, Teruhisa Horita, Natsuko Sakai, Tatsuya Kawada, Masayuki Dokiya

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The chemical stabilities of electrode-electrolyte interfaces have been investigated for the following two cases: (1) interaction between yttria-stabilized zirconia electrolyte and platinum electrode is selected as an example to confirm the validity of the present approach; (2) interaction between β″-alumina electrolyte-molybdenum electrode in AMTEC (alkali metal thermoelectric convertor): the chemical potential diagrams for the NaAlMoO system have been constructed to examine the transfer of sodium in the electrolyte-electrode interface vicinity as functions of partial pressure of oxygen and sodium.

Original language	English
Pages (from-to)	203-210
Number of pages	8
Journal	Solid State Ionics
Volume	78
Issue number	3-4
DOIs	https://doi.org/10.1016/0167-2738(95)00092-K
Publication status	Published - 1995 Jan 1
Externally published	Yes

Keywords

AMTEC
Electrode-electrolyte interaction
Molybdenum electrode
Platinum electrode
YSZ
β-alumina

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1016/0167-2738(95)00092-K

Cite this

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abstract = "The chemical stabilities of electrode-electrolyte interfaces have been investigated for the following two cases: (1) interaction between yttria-stabilized zirconia electrolyte and platinum electrode is selected as an example to confirm the validity of the present approach; (2) interaction between β″-alumina electrolyte-molybdenum electrode in AMTEC (alkali metal thermoelectric convertor): the chemical potential diagrams for the NaAlMoO system have been constructed to examine the transfer of sodium in the electrolyte-electrode interface vicinity as functions of partial pressure of oxygen and sodium.",

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T1 - Chemical thermodynamic stabilities of electrode/electrolyte interfaces of high temperature electrochemical cells

AU - Yokokawa, Harumi

AU - Horita, Teruhisa

AU - Sakai, Natsuko

AU - Kawada, Tatsuya

AU - Dokiya, Masayuki

PY - 1995/1/1

Y1 - 1995/1/1

N2 - The chemical stabilities of electrode-electrolyte interfaces have been investigated for the following two cases: (1) interaction between yttria-stabilized zirconia electrolyte and platinum electrode is selected as an example to confirm the validity of the present approach; (2) interaction between β″-alumina electrolyte-molybdenum electrode in AMTEC (alkali metal thermoelectric convertor): the chemical potential diagrams for the NaAlMoO system have been constructed to examine the transfer of sodium in the electrolyte-electrode interface vicinity as functions of partial pressure of oxygen and sodium.

AB - The chemical stabilities of electrode-electrolyte interfaces have been investigated for the following two cases: (1) interaction between yttria-stabilized zirconia electrolyte and platinum electrode is selected as an example to confirm the validity of the present approach; (2) interaction between β″-alumina electrolyte-molybdenum electrode in AMTEC (alkali metal thermoelectric convertor): the chemical potential diagrams for the NaAlMoO system have been constructed to examine the transfer of sodium in the electrolyte-electrode interface vicinity as functions of partial pressure of oxygen and sodium.

KW - AMTEC

KW - Electrode-electrolyte interaction

KW - Molybdenum electrode

KW - Platinum electrode

KW - YSZ

KW - β-alumina

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ER -

Chemical thermodynamic stabilities of electrode/electrolyte interfaces of high temperature electrochemical cells

Abstract

Keywords

ASJC Scopus subject areas

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