Chelating of titanium by lactic acid in the water-soluble diammonium tris(2-hydroxypropionato)titanate(IV)

M. Kakihana, K. Tomita, V. Petrykin, M. Tada, S. Sasaki, Y. Nakamura

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    71 Citations (Scopus)

    Abstract

    Stable water-soluble diammonium tris(2-hydroxypropionato)titanate(IV) [ammonium trilactatotitanate(IV)], (NH4)2[Ti(C 3H4O3)3], was prepared in the crystalline form. According to the X-ray single-crystal diffraction data, this compound crystallizes in the cubic cell with a = 11.649(4) Å, space group P213 (no. 198), and has Z = 4 molecules per unit cell. The 13C NMR data and Raman and IR spectra support the determined structure. The absence of non-bonded functional groups restricts the formation of oligomers in contrast to the reported speciation of citratoperoxotitanate(IV) complexes.

    Original languageEnglish
    Pages (from-to)4546-4548
    Number of pages3
    JournalInorganic chemistry
    Volume43
    Issue number15
    DOIs
    Publication statusPublished - 2004 Jul 26

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry

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