@article{0d860c1ff16d43cd88286ea8d9cdc459,
title = "Charge transfer in dissociating iodomethane and fluoromethane molecules ionized by intense femtosecond X-ray pulses",
abstract = "Ultrafast electron transfer in dissociating iodomethane and fluoromethane molecules was studied at the Linac Coherent Light Source free-electron laser using an ultraviolet-pump, X-ray-probe scheme. The results for both molecules are discussed with respect to the nature of their UV excitation and different chemical properties. Signatures of long-distance intramolecular charge transfer are observed for both species, and a quantitative analysis of its distance dependence in iodomethane is carried out for charge states up to I21+. The reconstructed critical distances for electron transfer are in good agreement with a classical over-the-barrier model and with an earlier experiment employing a near-infrared pump pulse.",
author = "Rebecca Boll and Benjamin Erk and Ryan Coffee and Sebastian Trippel and Thomas Kierspel and C{\'e}dric Bomme and Bozek, {John D.} and Mitchell Burkett and Sebastian Carron and Ferguson, {Ken R.} and Lutz Foucar and Jochen K{\"u}pper and Tatiana Marchenko and Catalin Miron and Minna Patanen and Timur Osipov and Sebastian Schorb and Marc Simon and Michelle Swiggers and Simone Techert and Kiyoshi Ueda and Christoph Bostedt and Daniel Rolles and Artem Rudenko",
note = "Funding Information: M.B., D.R., and A.R. were supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical, Geological, and Biological Sciences, under Contract No. DE-FG02-86ER1349. C.B. was supported by Grant No. DE-AC02-06CH11357 from the same agency. A.R. also acknowledges support from the National Science Foundation EPSCoR Track II Award No. IIA-1430493. D.R. also acknowledges support through the Helmholtz Young Investigator program. The authors are grateful to Sang-Kil Son for providing the calculated binding energy values, and to the LCLS stafffor their support and hospitality during the experiment. Publisher Copyright: {\textcopyright} 2016 Author(s). Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2016",
month = jul,
day = "1",
doi = "10.1063/1.4944344",
language = "English",
volume = "3",
journal = "Structural Dynamics",
issn = "2329-7778",
publisher = "AAPM - American Association of Physicists in Medicine",
number = "4",
}