Charge instability in 1D halogen-bridged binuclear metal complex

T. Mitani, Y. Wada, M. Yamashita, K. Toriumi, A. Kobayashi, H. Kobayashi

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Single crystals of 1D halogen-bridged binuclear platinum complex, K4[Pt2(pop)4Cl]·3H2O, where pop=P2O5H22-, have been investigated by defused X-ray scattering, reflectivity and luminescence measurements. Compared with the halogen-bridged mononuclear metal complexes, several unusual behaviors are observed, which are responsible for an additional charge modulation in the charge density wave state. From the viewpoint of the extended Peierls-Hubbard model, they are reduced to the result of a competition between the electron-electron repulsive energy in binuclear Pt-Pt sites and the energy gain due to chlorine ion displacement.

Original languageEnglish
Pages (from-to)291-294
Number of pages4
JournalSynthetic Metals
Volume64
Issue number2-3
DOIs
Publication statusPublished - 1994 Jun
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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    Mitani, T., Wada, Y., Yamashita, M., Toriumi, K., Kobayashi, A., & Kobayashi, H. (1994). Charge instability in 1D halogen-bridged binuclear metal complex. Synthetic Metals, 64(2-3), 291-294. https://doi.org/10.1016/0379-6779(94)90126-0